(2-Methylallyl)triphenylphosphonium chloride

Base Information

• Chemical Name: (2-Methylallyl)triphenylphosphonium chloride
• CAS No.: 4303-59-7
• Molecular Formula: C22H22 P . Cl
• Molecular Weight: 352.843
• Hs Code.: 2931900090
• European Community (EC) Number: 224-313-9
• Mol file: 4303-59-7.mol

Synonyms:4303-59-7;(2-Methylallyl)triphenylphosphonium chloride;2-Methylallyl triphenylphosphonium chloride;C22H22P.Cl;SCHEMBL2448865;C22-H22-P.Cl;AKOS024318885;(2-Methylallyl)triphenylphosphoniumchloride;(2-Methallyl)-triphenylphosphonium chloride;2-methylallyl(triphenyl)phosphonium chloride;FT-0604636;2-methylprop-2-enyl(triphenyl)phosphanium;chloride;2-methylprop-2-enyl(triphenyl)phosphonium chloride;A826113

Chemical Property of (2-Methylallyl)triphenylphosphonium chloride

Chemical Property:

• Melting Point: 217-219°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 1.56060
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 352.1147654
• Heavy Atom Count: 24
• Complexity: 322

Purity/Quality:

98%,99%, ^*data from raw suppliers

(2-METHYLALLYL)-TRIPHENYLPHOSPHONIUM CHLORIDE AldrichCPR ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-]

Technology Process of (2-Methylallyl)triphenylphosphonium chloride

There total 4 articles about (2-Methylallyl)triphenylphosphonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.5%

triphenylphosphine (603-35-0) + Methacryloyl chloride (920-46-7,26937-45-1) → 2-methylallyltriphenylphosphonium chloride (4303-59-7)

Guidance literature:

In 5,5-dimethyl-1,3-cyclohexadiene; for 19h; Reflux; Large scale;

Reference yield:

triphenylphosphine (603-35-0) + 3-Chloro-2-methylpropene (563-47-3) → 2-methylallyltriphenylphosphonium chloride (4303-59-7)

Guidance literature:

In benzene;

DOI:10.1021/ja00873a027

Reference yield:

triphenylphosphine (603-35-0) + 3-Chloro-2-methylpropene (563-47-3) → (2-methylprop-1-en-1-yl)triphenylphosphonium chloride (42855-48-1) + 2-methylallyltriphenylphosphonium chloride (4303-59-7)

Guidance literature:

With N-benzyl-trimethylammonium hydroxide; Yield given. Multistep reaction; 1.) reflux, 24 h, 2.) acetonitrile, reflux, 2 h;

DOI:10.1021/ja00396a031

upstream raw materials:

triphenylphosphine

3-Chloro-2-methylpropene

Methacryloyl chloride

Downstream raw materials:

[Pt(C6H4-2-PPh2-η2-C(H)=CMe2)Cl2]

1,3-Dimethoxy-2-((Z)-3-methyl-buta-1,3-dienyl)-benzene

2',6'-dimethoxy-1'-((E)-3-methylbuta-1,3-dienyl)benzene

(1E)-1-cyclohexyl-3,3-dimethyl-1,3-butadiene

Refernces

• 1、 Kampmeier, J. A.,Harris, S. H.,Rodehorst, R. M.. "Reaction of α,β-Unsaturated Acid Chlorides with Tris(triphenylphosphine)chlororhodium(I): Formation of Phosphonium Salts". . p. 1478 - 1485. Retrieved 2007/10/02.