Diazene, bis(2-ethylphenyl)-, 1-oxide

Base Information

• Chemical Name: Diazene, bis(2-ethylphenyl)-, 1-oxide
• CAS No.: 64287-80-5
• Molecular Formula: C16H18N2O
• Molecular Weight: 254.332
• Mol file: 64287-80-5.mol

Synonyms:o,o'-diethyl-azoxybenzene;2.2'-Diethyl-azoxybenzol;2,2'-Diethyl-azoxybenzol;

Chemical Property of Diazene, bis(2-ethylphenyl)-, 1-oxide

Chemical Property:

• PSA: 41.11000
• LogP: 5.26030

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diazene, bis(2-ethylphenyl)-, 1-oxide

There total 10 articles about Diazene, bis(2-ethylphenyl)-, 1-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.35%

ortho-ethylaniline (578-54-1) → Bis(2-ethylphenyl)diazene 1-oxide (64287-80-5)

Guidance literature:

With dihydrogen peroxide; In acetonitrile; at 20 ℃; for 24h;

DOI:10.1039/c4gc02123a

Reference yield: 84.0%

2-nitro(ethylbenzene) (612-22-6) → ortho-ethylaniline (578-54-1) + Bis(2-ethylphenyl)diazene 1-oxide (64287-80-5)

Guidance literature:

With ammonium chloride; zinc; In water; at 80 ℃; for 24h; Catalytic behavior; Inert atmosphere;

Reference yield: 40.0%

2-nitro(ethylbenzene) (612-22-6) + nitrobenzene (98-95-3,26969-40-4) → azoxybenzene (495-48-7,55599-32-1) + 1,2-bis(2-ethylphenyl)diazene (61653-34-7) + Bis(2-ethylphenyl)diazene 1-oxide (64287-80-5)

Guidance literature:

With ammonium chloride; zinc; In water; at 80 ℃; for 24h; Catalytic behavior; Inert atmosphere;

upstream raw materials:

1,2-bis(2-ethylphenyl)diazene

1-ethyl-2-nitrosobenzene

ortho-ethylaniline

2-nitro(ethylbenzene)

Refernces

• 1、 Singh, Bhawan,Mandelli, Dalmo,Pescarmona, Paolo P.. "Efficient and Selective Oxidation of Aromatic Amines to Azoxy Derivatives over Aluminium and Gallium Oxide Catalysts with Nanorod Morphology". . p. 593 - 601. Retrieved 2019/11/13.
• 2、 Ghosh, Shilpi,Acharyya, Shankha S.,Sasaki, Takehiko,Bal, Rajaram. "Room temperature selective oxidation of aniline to azoxybenzene over a silver supported tungsten oxide nanostructured catalyst". . p. 1867 - 1876. Retrieved 2015/03/18.