Chlorine fluoride

Base Information

• Chemical Name: Chlorine fluoride
• CAS No.: 7790-89-8
• Molecular Formula: ClF
• Molecular Weight: 54.4514
• Hs Code.: 2812199000
• European Community (EC) Number: 232-229-9
• UNII: UE4699O6C6
• DSSTox Substance ID: DTXSID50894057
• Nikkaji Number: J96.029B
• Wikipedia: Chlorine fluoride,Chlorine monofluoride,Chlorine_monofluoride
• Wikidata: Q417146
• Mol file: 7790-89-8.mol

Synonyms:Chlorine fluoride;Chlorine monofluoride;7790-89-8;Chlorine fluoride (ClF);35Chlorine monofluoride;UNII-UE4699O6C6;UE4699O6C6;EINECS 232-229-9;CLF;fluoridochlorine;Cl-F;FLUORINE CHLORIDE;CHLORINEMONOFLUORIDE;Chlorine monofluoride 99%;CHLOROFLUORIDE (CLF);FLUORINE CHLORIDE (FCL);CHEBI:30121;DTXSID50894057;CHLORINE MONOFLUORIDE [MI];CHLORINE MONOFLUORIDE (CLF);MFCD00042565;FT-0623606;Q417146;21377-80-0

Chemical Property of Chlorine fluoride

Chemical Property:

• Vapor Pressure: 217000mmHg at 25°C
• Melting Point: -155.6oC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.2g/cm³
• LogP: 1.10970
• Water Solubility.: violent reaction with H2O [MER06]
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 53.9672559
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

98%Min ^*data from raw suppliers

Chlorine monofluoride 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O
• Hazard Codes: O
• Statements: 8-14-23-36/37/38
• Safety Statements: 3/7-9-15-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Corrosive Gases
• Canonical SMILES: FCl

Technology Process of Chlorine fluoride

There total 64 articles about Chlorine fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

chlorine (7782-50-5) + fluorine (7782-41-4) → chlorine monofluoride (7790-89-8)

Guidance literature:

In gas; byproducts: ClO2, ClF3; Irradiation (UV/VIS); pulsed irradiation of gaseous stoichiometric mixt. of F2 and Cl2 in a closed space at room temp. (light pulses lasting 5E-6 to E-3 s with λ=200-450 nm); impurities detected by spectroscopic methods; presence of ;

Reference yield: 72.0%

chlorine trifluoride (7790-91-2) → chlorine monofluoride (7790-89-8)

Guidance literature:

With chlorine; at 300 ℃; for 48h; Autoclave; Inert atmosphere;

DOI:10.1016/j.jfluchem.2019.109416

Reference yield: 45.0%

potassium chlorate (3811-04-9) + fluorine (7782-41-4) → perchloryl fluoride (7616-94-6) + dichlorine hexaoxide + chlorine dioxide (10049-04-4,25052-55-5) + chlorine monofluoride (7790-89-8) + chlorine (7782-50-5)

Guidance literature:

In neat (no solvent); byproducts: O2; transport reaction: passing F2-N2 mixture over KClO3 at 25 - 60°C;; washing with NaOH; passing ClO3F through Na2S2O3 soln.; drying over NaOH and P2O5;;

upstream raw materials:

nitrosylchloride

fluorine

nickel dichloride

cesium chloride

Downstream raw materials:

Trifluoromethylsulfenyl chloride

fluorosulfonylchloride

fluorosulfonyl fluoride

arsenic pentafluoride

Refernces

• 1、 Cooke, Stephen A.,Cotti, Gina,Hinds, Kelvin,Holloway, John H.,Legon,Lister, David G.. "Rotational spectrum and molecular properties of the dinitrogen-chlorine monofluoride complex". . p. 2671 - 2676. Retrieved 1996.
• 2、 Hinds, K.,Holloway, J. H.,Legon, A. C.. "The complex OC...ClF identified as a pre-chemical intermediate by rotational spectroscopy of carbon monoxide-chlorine monofluoride mixtures". . p. 407 - 414. Retrieved 1995.
• 3、 Zelenov,Aparina,Kashtanov,Shestakov,Gershenzon. "Kinetic mechanism of ClONO2 uptake on polycrystalline film of NaCl". . p. 6771 - 6780. Retrieved 2008/10/09.
• 4、 Mueller, B. G.. "Synthese binaerer und ternaerer fluoride". . . Retrieved 2008/10/08.