Mercury, bis(2-methoxyphenyl)-

Base Information

• Chemical Name: Mercury, bis(2-methoxyphenyl)-
• CAS No.: 6535-18-8
• Molecular Formula: C14H14HgO2
• Molecular Weight: 414.854
• Mol file: 6535-18-8.mol

Synonyms:

Chemical Property of Mercury, bis(2-methoxyphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Mercury, bis(2-methoxyphenyl)-

There total 10 articles about Mercury, bis(2-methoxyphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

mercury(II) diacetate (1600-27-7) + 2-tri-n-butylstannylanisole (86487-17-4) → bis(o-methoxyphenyl)mercury (6535-18-8)

Guidance literature:

In tetrahydrofuran; stirring at room temp. for 5 h;; solvent removed; EtOH added; crystd. from light petroleum;;

Reference yield: 73.0%

mercury dibromide + 2-methoxyphenyllithium (31600-86-9) → bis(o-methoxyphenyl)mercury (6535-18-8)

Guidance literature:

In diethyl ether; a soln. of Li-compound in diethyl ether (40°C0 was added dropwiseto a stirred slurry of HgBr2 in diethyl ether kept at 0°C, the s uspn. was allowed to warm to room temp., stirred for 12 h (inert atm.); H2O was added, the aq. layer was extd. with diethyl ether, the organic layer was concd., recrystd. from toluene; elem. anal.;

DOI:10.1021/ja011472w

Reference yield:

→ bis(o-methoxyphenyl)mercury (6535-18-8)

Guidance literature:

With ethanol; potassium thioacyanate;

upstream raw materials:

2-bromoanisole

methyl iodide

2-methoxy-phenylamine

mercury(II) diacetate

Downstream raw materials:

[PtCl(C₆H₄OCH₃)(CO)PCH₃(C₆H₅)2]

(2-methoxyphenyl)dichloroborane

(2-methoxyphenyl)(4-nitrophenyl)methanone

Ethyl 1-(o-methoxyphenyl)-2-oxocyclopentanecarboxylate

Refernces