POLY(HEXAMETHYLENEVINYLENE) MIXTURE OF&

Base Information

• Chemical Name: POLY(HEXAMETHYLENEVINYLENE) MIXTURE OF&
• CAS No.: 65909-92-4
• Molecular Formula: C8H12
• Molecular Weight: 108.183
• Mol file: 65909-92-4.mol

Synonyms:7-octen-1-yne;Poly(hexamethylenevinylene),mixture of linear and cyclic forms;1-Octen-7-yne;Oct-1-en-7-in;

Chemical Property of POLY(HEXAMETHYLENEVINYLENE) MIXTURE OF&

Chemical Property:

• Boiling Point: 122 °C
• PSA: 0.00000
• Density: 0.91 g/mL at 25oC(lit.)
• LogP: 2.36600

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POLY(HEXAMETHYLENEVINYLENE) MIXTURE OF&

There total 1 articles about POLY(HEXAMETHYLENEVINYLENE) MIXTURE OF& which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bicyclo<5.1.0>octan-2-one tosylhydrazone (73733-09-2) → vinylcyclohexane (695-12-5,25498-06-0) + 1-octen-7-yne (65909-92-4) + bicyclo<4.2.0>oct-6-ene (37680-26-5)

Guidance literature:

With sodium methylate; at 160 - 170 ℃; under 0.5 Torr;

Reference yield: 99.0%

1-octen-7-yne (65909-92-4) + 1,2-Diiodobenzene (615-42-9) → 1,2-bis(1-octen-7-yne)benzene (168642-34-0)

Guidance literature:

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; for 48h; Ambient temperature;

DOI:10.1016/0022-328X(95)00107-2

Reference yield: 75.0%

1-octen-7-yne (65909-92-4) + trimethylaluminum (75-24-1) + benzoic acid anhydride (93-97-0) → C16H20O2 (1034980-28-3)

Guidance literature:

1-octen-7-yne; trimethylaluminum; With zirconocene dichloride; water; In dichloromethane; toluene; at 0 ℃; for 6.5h; Inert atmosphere;

With methyl(tert-butylperoxy)zinc; In dichloromethane; toluene; at 0 ℃; for 2h; Inert atmosphere;

benzoic acid anhydride; With tributylphosphine; In dichloromethane; toluene; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/ja803480b

upstream raw materials:

bicyclo<5.1.0>octan-2-one tosylhydrazone

Downstream raw materials:

octadec-17-ene-9,11-diynoic acid

[((E)-Octa-1,7-dienyl)sulfanyl]-benzene

1,2-bis(1-octen-7-yne)benzene

(+/-)-cis-1,2,3,4,4a,5,6,8a-octahydro-naphthalene

Refernces