1,1'-(3-Methyl-1-propene-1,3-diyl)bis-benzene

Base Information

• Chemical Name: 1,1'-(3-Methyl-1-propene-1,3-diyl)bis-benzene
• CAS No.: 7614-93-9
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• DSSTox Substance ID: DTXSID40871195
• Mol file: 7614-93-9.mol

Synonyms:DTXSID40871195;1,1'-(3-Methyl-1-propene-1,3-diyl)bis-benzene

Chemical Property of 1,1'-(3-Methyl-1-propene-1,3-diyl)bis-benzene

Chemical Property:

• Melting Point: 47.5°C
• Refractive Index: 1.5900
• Boiling Point: 309.3°Cat760mmHg
• Flash Point: 145.2°C
• PSA: 0.00000
• Density: 0.999g/cm³
• LogP: 4.50350
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 208.125200510
• Heavy Atom Count: 16
• Complexity: 204

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C=CC1=CC=CC=C1)C2=CC=CC=C2

Technology Process of 1,1'-(3-Methyl-1-propene-1,3-diyl)bis-benzene

There total 239 articles about 1,1'-(3-Methyl-1-propene-1,3-diyl)bis-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) → 1,3-diphenyl-1-butene (7614-93-9) + benzaldehyde (100-52-7) + acetophenone (98-86-2)

Guidance literature:

With dihydrogen peroxide; palladium dichloride; 3-(3-cyanopropyl)-1-methylimidazol-3-ium bis(trifluoromethane)sulfonimide; In water; at 60 ℃; for 3h;

DOI:10.1039/c0gc00945h

Reference yield: 59.0%

1-Phenylethanol (98-85-1,13323-81-4) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + ethylbenzene (100-41-4,27536-89-6) + bis(1-phenylethyl)ether (93-96-9) + 1,3-diphenyl-1-butene (7614-93-9) + 1-methyl-3-phenylindan (6416-39-3)

Guidance literature:

With HY-100 zeolite; In tetrachloromethane; at 78 ℃; for 17h; Mechanism; Product distribution; other benzylic alcohols;

Reference yield: 57.0%

acetophenone (98-86-2) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-methyl-4-(1-phenylethyl)benzene (3717-68-8) + 1,3-diphenyl-1-butene (7614-93-9)

Guidance literature:

With trifluorormethanesulfonic acid; hydrogen; silver trifluoromethanesulfonate; C₂₃H₂₄ClIrN₄; In toluene; at 80 ℃; for 22h; under 750.075 Torr;

DOI:10.1021/acscatal.1c00740

upstream raw materials:

[(S)-5-Oxo-1-((S)-1-phenyl-ethyl)-pyrrolidin-2-yl]-acetic acid

(triphenyl)(prop-1-enyl)phosphonium bromide

benzaldehyde

phenyllithium

Downstream raw materials:

2-Phenylpropanal

benzaldehyde

benzoic acid

1,3-diphenylbutane

Refernces

• 1、 Murata, Kei,Araki, Mizuki,Inagaki, Akiko,Akita, Munetaka. "Syntheses, photophysical properties, and reactivities of novel bichromophoric Pd complexes composed of Ru(ii)-polypyridyl and naphthyl moieties". . p. 6989 - 7001. Retrieved 2013.
• 2、 Albrecht, Martin,Alshakova, Iryna D.. "Cascade Reductive Friedel-Crafts Alkylation Catalyzed by Robust Iridium(III) Hydride Complexes Containing a Protic Triazolylidene Ligand". . p. 8999 - 9007. Retrieved 2021/07/31.
• 3、 Li, Xiaowei,Li, Yuxiu,Zhang, Zhong,Shi, Xiaolin,Liu, Ruihua,Wang, Zemin,Li, Xiangqian,Shi, Dayong. "Nickel-Catalyzed Arylation of C(sp3)-O Bonds in Allylic Alkyl Ethers with Organoboron Compounds". . p. 6612 - 6616. Retrieved 2021/09/02.