1,1-Diethylhydrazine

Base Information

• Chemical Name: 1,1-Diethylhydrazine
• CAS No.: 616-40-0
• Molecular Formula: C4H12N2
• Molecular Weight: 88.1527
• DSSTox Substance ID: DTXSID00870700
• Nikkaji Number: J47.974H
• Wikidata: Q63408830
• Mol file: 616-40-0.mol

Synonyms:1,1-Diethylhydrazine;616-40-0;Diethylhydrazine;N,N-Diethylhydrazine;Hydrazine, 1,1-diethyl-;Hydrazine, diethyl-;CCRIS 4556;AI3-26686;40626-95-7;1,1-diethyldiazane;N,N-diethyl-hydrazine;Hydrazine,1,1-diethyl-;DTXSID00870700;MFCD02752099;STL355871;AKOS000271029;LS-188175;A810276;Q63408830

Chemical Property of 1,1-Diethylhydrazine

Chemical Property:

• Vapor Pressure: 16.3mmHg at 25°C
• Refractive Index: 1.44
• Boiling Point: 119 °C at 760 mmHg
• Flash Point: 22.8 °C
• PSA: 29.26000
• Density: 0.835 g/cm³
• LogP: 0.90220
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 88.100048391
• Heavy Atom Count: 6
• Complexity: 24.7

Purity/Quality:

98%min ^*data from raw suppliers

1,1-Diethylhydrazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCN(CC)N
• Uses: 1,1-Diethylhydrazine is used in preparation of Chiral Myrtanyl Sulfonamides.

Technology Process of 1,1-Diethylhydrazine

There total 1 articles about 1,1-Diethylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-Nitrosodiethylamine (55-18-5) → N,N-diethylhydrazine (616-40-0) + diethylamine (109-89-7)

Guidance literature:

With titanium(III) chloride; ammonium acetate; In water; for 1h; Product distribution; Ambient temperature; variation of reaction conditions ( pH <1, pH=9.4 );

DOI:10.1021/jo00193a007

Reference yield: 93.0%

N,N-diethylhydrazine (616-40-0) + Diphenylphosphinic chloride (1499-21-4) → 1,1-diethyl-2-diphenylphosphinoylhydrazine (88240-69-1)

Guidance literature:

With triethylamine; In dichloromethane;

Reference yield: 92.0%

N,N-diethylhydrazine (616-40-0) + phenyl isothiocyanate (103-72-0) → 1,1-diethyl-4-phenylthiosemicarbazide (21075-60-5)

Guidance literature:

In diethyl ether; Ambient temperature;

upstream raw materials:

N-Nitrosodiethylamine

Downstream raw materials:

1,1-diethyl-4-phenyl semicarbazide

aldehyde diethylhydrazone

C₁₀H₂₂N₄S₄

α-Aethyl-acrolein-N,N-diaethyl-hydrazon

Refernces