MegastigM-7-ene-3,5,6,9-tetraol

Base Information

• Chemical Name: MegastigM-7-ene-3,5,6,9-tetraol
• CAS No.: 680617-50-9
• Molecular Formula: C₁₃H₂₄O₄
• Molecular Weight: 244.331
• Mol file: 680617-50-9.mol

Synonyms:7-Megastigmene-3,5,6,9-tetrol;

Chemical Property of MegastigM-7-ene-3,5,6,9-tetraol

Chemical Property:

• Boiling Point: 344.9±42.0 °C(Predicted)
• PKA: 13.77±0.70(Predicted)
• PSA: 80.92000
• Density: 1.203±0.06 g/cm3(Predicted)
• LogP: 0.58640

Purity/Quality:

98%min ^*data from raw suppliers

Megastigm-7-Ene-3,5,6,9-Tetraol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of MegastigM-7-ene-3,5,6,9-tetraol

There total 12 articles about MegastigM-7-ene-3,5,6,9-tetraol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(3R,5S,6S,7E,9S)-megastigman-7-ene-3,5,6,9-tetraol 9-O-β-D-glucopyranoside (1033434-17-1) → (3R,5S,6S,7E,9S)-megastiman-7-ene-3,5,6,9-tetraol (1033400-30-4,680617-50-9)

Guidance literature:

With water; Enzymatic reaction;

DOI:10.1016/j.phytochem.2008.01.020

Reference yield: 69.0%

trans-(3S,5R,6R,9S)-megastigman-7-ene-3,5,6,9-tetraol 9-O-β-D-glucopyranoside → D-Glucose (2280-44-6) + (3S,5R,6R,7E,9S)-3,5,6,9-tetrahydroxy-7-en-megastigmane (276870-26-9,680617-50-9)

Guidance literature:

With hesperidinase; water; at 37 ℃; for 12h;

DOI:10.1016/S0031-9422(02)00614-3

Reference yield: 63.0%

trans-(3S,5R,6R,9S)-megastigman-7-ene-3,5,6,9-tetraol 3-O-β-D-glucopyranoside → D-Glucose (2280-44-6) + (3S,5R,6R,7E,9S)-3,5,6,9-tetrahydroxy-7-en-megastigmane (276870-26-9,680617-50-9)

Guidance literature:

With hesperidinase; water; at 37 ℃; for 24h;

DOI:10.1016/S0031-9422(02)00614-3

upstream raw materials:

(3R,5S,6S,7E,9S)-megastigman-7-ene-3,5,6,9-tetraol 9-O-β-D-glucopyranoside

(3R,5S,6S,7E,9R)-megastigman-7-ene-3,5,6,9-tetraol 3-O-β-D-glucopyranoside

(E)-β-ionone

(3E)-4-(2,6,6-trimethylcyclohexa-1,3-dien-1-yl)but-3-en-2-one

Refernces

• 1、 Lazaro, Aline S.,Ribeiro, Pedro H. Zana,Sairre, Mirela I.,Donate, Paulo M.. "New Approach to the Synthesis of the Natural Product Aripuanin". . p. 1374 - 1378. Retrieved 2015/05/26.
• 2、 Nakamura, Seikou,Zhang, Yi,Matsuda, Hisashi,Ninomiya, Kiyofumi,Muraoka, Osamu,Yoshikawa, Masayuki. "Chemical structures and hepatoprotective effects of constituents from the leaves of Salacia chinensis". experimental part. p. 1020 - 1028. Retrieved 2011/10/12.