METHYL 2-METHOXYACRYLATE

Base Information

• Chemical Name: METHYL 2-METHOXYACRYLATE
• CAS No.: 7001-18-5
• Molecular Formula: C5H8O3
• Molecular Weight: 116.117
• Mol file: 7001-18-5.mol

Synonyms:Methyl 2-methoxyacrylate;2-Propenoic acid,2-methoxy-,methyl ester;methoxymethyleneacetic acid methyl ester;methyl pyruvate methyl enol ether;Methyl 2-methoxypropenoate;methyl methoxyacrylate;2-methoxy-acrylic acid methyl ester;2-Methoxy-propensaeure-methylester;

Chemical Property of METHYL 2-METHOXYACRYLATE

Chemical Property:

• Boiling Point: 55-56 °C(Press: 13 Torr)
• PSA: 35.53000
• Density: 1.0702 g/cm3(Temp: 18.950009765625 °C)
• LogP: 0.31950

Purity/Quality:

99%min ^*data from raw suppliers

methyl2-methoxyacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL 2-METHOXYACRYLATE

There total 4 articles about METHYL 2-METHOXYACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

2,3-dimethoxy-1,3-butadiene (3588-31-6) → Dimethyl oxalate (553-90-2) + methyl 2-methoxyacrylate (7001-18-5) + 3-Methoxy-3-(1-methoxyethenyl)-1,2-dioxolane (143429-27-0) + 3-Methoxy-3-(1-methoxyethenyl)-1,2,4-trioxolane (143429-26-9)

Guidance literature:

With ozone; In pentane; at -30 ℃;

DOI:10.1021/jo00047a007

Reference yield: 17.0%

2,3-dimethoxy-1,3-butadiene (3588-31-6) → Dimethyl oxalate (553-90-2) + methyl 2-methoxyacrylate (7001-18-5) + methoxymethyl hydroperoxide (10027-72-2) + 2,3,3-Trimethoxy-4-hydroxy-1-butene (143429-25-8)

Guidance literature:

With ozone; In methanol; at -30 ℃;

DOI:10.1021/jo00047a007

Reference yield: 17.0%

methanol (67-56-1) + 2,3-dimethoxy-1,3-butadiene (3588-31-6) → Dimethyl oxalate (553-90-2) + methyl 2-methoxyacrylate (7001-18-5) + methoxymethyl hydroperoxide (10027-72-2) + 2,3,3-Trimethoxy-4-hydroxy-1-butene (143429-25-8)

Guidance literature:

With ozone; at -30 ℃;

DOI:10.1021/jo00047a007

upstream raw materials:

methanol

2,3-dimethoxy-1,3-butadiene

Downstream raw materials:

2-methoxyacrylic acid

methyl 2,2-dimethoxypropionate

α-methoxy-trans-cinnamic acid methyl ester

(Z)-2-Methoxy-3-m-tolyl-acrylic acid methyl ester

Refernces

• 1、 -. "2-Alkoxyacrylate process". . . Retrieved 2008/06/13.