cis-1,2,3-Triphenylaziridine

Base Information

• Chemical Name: cis-1,2,3-Triphenylaziridine
• CAS No.: 7042-42-4
• Molecular Formula: C₂₀H₁₇N
• Molecular Weight: 271.362
• European Community (EC) Number: 622-347-2
• DSSTox Substance ID: DTXSID80364339
• Nikkaji Number: J1.295.930C
• Mol file: 7042-42-4.mol

Synonyms:cis-1,2,3-Triphenylaziridine;7042-42-4;(2S,3R)-1,2,3-triphenylaziridine;cis-1.2.3-triphenylaziridine;SCHEMBL2775830;DTXSID80364339;1,2alpha,3alpha-Triphenylaziridine

Chemical Property of cis-1,2,3-Triphenylaziridine

Chemical Property:

• Melting Point: 98-102 °C(lit.)
• PSA: 3.01000
• LogP: 5.05420
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 271.136099547
• Heavy Atom Count: 21
• Complexity: 297

Purity/Quality:

97% ^*data from raw suppliers

CIS-1,2,3-TRIPHENYLAZIRIDINE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2C(N2C3=CC=CC=C3)C4=CC=CC=C4
• Isomeric SMILES: C1=CC=C(C=C1)[C@H]2[C@H](N2C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of cis-1,2,3-Triphenylaziridine

There total 3 articles about cis-1,2,3-Triphenylaziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4,5-cis-2,3,4,5-tetraphenyloxazolidine → 2,3-trans-1,2,3-triphenylaziridine (968-02-5,7042-42-4,34310-77-5)

Guidance literature:

In benzene; Irradiation;

DOI:10.1246/cl.1981.1585

Reference yield:

erythro-2-(N-phenylamino)-1,2-diphenylethanol (82940-37-2,84327-65-1,84327-66-2,89357-29-9,89357-30-2,151214-47-0,151214-48-1,210571-76-9) → 2,3-trans-1,2,3-triphenylaziridine (968-02-5,7042-42-4,34310-77-5)

Guidance literature:

Multi-step reaction with 2 steps

2: benzene / Irradiation

In benzene;

DOI:10.1246/cl.1981.1585

Reference yield:

→ (2R,3R)-1,2,3-Triphenyl-aziridine (968-02-5,7042-42-4,34310-77-5)

Guidance literature:

Triphenylaziridin 1, Pyrolyse;

DOI:10.1039/C29710001188

upstream raw materials:

erythro-2-(N-phenylamino)-1,2-diphenylethanol

Downstream raw materials:

1,2,5-Triphenylpyrrol-3,4-dicarbonsaeure-dimethylester

3,4-bis(methoxycarbonyl)-2,5-trans-1,3,5-triphenyl-3-pyrroline

(2S,3R,4S,5S)-4-Diethoxymethyl-1,2,5-triphenyl-pyrrolidine-3-carbonitrile

(2S,3S,4S,5S)-4-Diethoxymethyl-1,2,5-triphenyl-pyrrolidine-3-carbonitrile

Refernces