N-Hydroxy-2,4-dinitrobenzenamine

Base Information

• Chemical Name: N-Hydroxy-2,4-dinitrobenzenamine
• CAS No.: 51348-06-2
• Molecular Formula: C6H5N3O5
• Molecular Weight: 199.123
• UNII: K711S0X7TI
• DSSTox Substance ID: DTXSID80199345
• Nikkaji Number: J1.662.408J
• Wikidata: Q27282029
• Mol file: 51348-06-2.mol

Synonyms:N-Hydroxy-2,4-dinitrobenzenamine;Benzenamine, N-hydroxy-2,4-dinitro-;51348-06-2;UNII-K711S0X7TI;K711S0X7TI;N-Hydroxy-2,4-dinitroaniline;SCHEMBL3132093;DTXSID80199345;IHUQJPKASFTOBM-UHFFFAOYSA-N;CS-11162;Q27282029

Chemical Property of N-Hydroxy-2,4-dinitrobenzenamine

Chemical Property:

• Vapor Pressure: 8.14E-07mmHg at 25°C
• Boiling Point: 391°Cat760mmHg
• Flash Point: 190.3°C
• Density: 1.753g/cm³
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 199.02292027
• Heavy Atom Count: 14
• Complexity: 235

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=C(C=C1[N+](=O)[O-])[N+](=O)[O-])NO

Technology Process of N-Hydroxy-2,4-dinitrobenzenamine

There total 5 articles about N-Hydroxy-2,4-dinitrobenzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2,4-dinitroanisole (119-27-7) → N-(2,4-dinitrophenyl)hydroxylamine (51348-06-2)

Guidance literature:

With hydroxylamine hydrochloride; sodium methylate; In methanol; for 19h; Heating;

DOI:10.1081/SCC-100105881

Reference yield:

2,4-dinitrophenyl phenyl ether (2486-07-9) → N-(2,4-dinitrophenyl)hydroxylamine (51348-06-2)

Guidance literature:

With hydroxylamine hydrochloride; sodium ethanolate;

Reference yield:

2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) → N-(2,4-dinitrophenyl)hydroxylamine (51348-06-2)

Guidance literature:

With hydroxylamine; In methanol; water; at 25 ℃; Rate constant; pH 8.00 to 10.00, ionic strength of 0.1 mol l^-1;

upstream raw materials:

2,4-dinitroanisole

2,4-dinitrophenyl phenyl ether

2,4-Dinitrofluorobenzene

hydroxylamine

Downstream raw materials:

5-nitrobenzofuroxan

2,4-Dinitroanilin

4-Nitrophenylene-1,2-diamine

1,2,4-trinitrobenzene

Refernces

• 1、 Zima, Vitezslav,Pytela, Oldrich,Vecera, Miroslav. "A STUDY OF NUCLEOPHILICITY IN SELECTED SYSTEMS". . p. 814 - 821. Retrieved 2007/10/02.