[Gallanetriyltris(methylene)]tris(trimethylsilane)

Base Information

• Chemical Name: [Gallanetriyltris(methylene)]tris(trimethylsilane)
• CAS No.: 72708-53-3
• Molecular Formula: C12H33GaSi3
• Molecular Weight: 331.374
• DSSTox Substance ID: DTXSID10531138
• Mol file: 72708-53-3.mol

Synonyms:72708-53-3;[Gallanetriyltris(methylene)]tris(trimethylsilane);DTXSID10531138;tris[(trimethylsilyl)methyl]gallium

Chemical Property of [Gallanetriyltris(methylene)]tris(trimethylsilane)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 330.11458
• Heavy Atom Count: 16
• Complexity: 170

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C[Ga](C[Si](C)(C)C)C[Si](C)(C)C

Technology Process of [Gallanetriyltris(methylene)]tris(trimethylsilane)

There total 1 articles about [Gallanetriyltris(methylene)]tris(trimethylsilane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ga(CH2Si(CH3)3)2Br (74251-17-5) + K(1+)*Ga(CH2Si(CH3)3)2H2(1-)=KGa(CH2Si(CH3)3)2H2 (87828-71-5) → gallium (7440-55-3) + tris(trimethylsilylmethyl)gallium (72708-53-3) + Ga(CH2Si(CH3)3)2H (87801-07-8)

Guidance literature:

In benzene; byproducts: H2, Si(CH3)4, KBr; Ga(CH2Si(CH3)3)2Br soln. added to KGa(CH2Si(CH3)3)2H2 soln. at room temp., stirred for 24 h, cooled to -196°C; fractionally distd., filtered, vacuum distd. at 110°C;

DOI:10.1021/om00080a004

Reference yield: 98.5%

tris(trimethylsilylmethyl)gallium (72708-53-3) + trimethylamine hydrochloride (593-81-7) → tetramethylsilane (75-76-3) + Ga(3+)*2CH2Si(CH3)3(1-)*Cl(1-)*N(CH3)3=Ga(CH2Si(CH3)3)2Cl*N(CH3)3 (72709-13-8)

Guidance literature:

In benzene; under N2 or Ar mixt. in stoich. quantity stirred at room temp. for 2 h; volatile components removed by vac. distn., crude product sublimed at 32°C; elem. anal.;

DOI:10.1021/ic50206a046

Reference yield: 95.0%

tris(trimethylsilylmethyl)gallium (72708-53-3) + C22H30N2O2 → C30H51GaN2O2Si2

Guidance literature:

In tetrahydrofuran; at 70 ℃; for 50h; Inert atmosphere;

DOI:10.1002/chem.201402358

upstream raw materials:

Ga(CH₂Si(CH₃)3)2Br

K⁽¹⁺⁾*Ga(CH₂Si(CH₃)3)2H₂^(1-)=KGa(CH₂Si(CH₃)3)2H₂

Downstream raw materials:

3,7-bis{3,5-bis(trifluoromethyl)phenyl}-2,6-bis(1,1-dimethylethyl)-4,4,8,8-tetrakis{(trimethylsilyl)methyl}-1,5,2λ(4),6λ(4),3,7,4λ(4),8λ(4)-dioxadithiadiazadigallocan

tetramethylsilane

((CH₃)3SiCH₂)2Ga(P(C₆H₅)2)

(C₆H₅)2AsGa(CH₂Si(CH₃)3)2

Refernces