6,6-Diethyl-fulvene

Base Information

• Chemical Name: 6,6-Diethyl-fulvene
• CAS No.: 7301-16-8
• Molecular Formula: C10H14
• Molecular Weight: 134.221
• DSSTox Substance ID: DTXSID50458613
• Nikkaji Number: J788.527J
• Wikidata: Q82282044
• Mol file: 7301-16-8.mol

Synonyms:6,6-diethyl-fulvene;5-(1-ethylpropylidene)-1,3-cyclopentadiene;7301-16-8;6,6-diethylfulvene;DTXSID50458613;XDCVKINZRQNSTP-UHFFFAOYSA-N;1-(1-Ethylpropylidene)-2,4-cyclopentadiene

Chemical Property of 6,6-Diethyl-fulvene

Chemical Property:

• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 134.109550447
• Heavy Atom Count: 10
• Complexity: 172

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(=C1C=CC=C1)CC

Technology Process of 6,6-Diethyl-fulvene

There total 1 articles about 6,6-Diethyl-fulvene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-dicyano-7-(1-ethyl-propylidene)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid diethyl ester → diethyl dicyanofumarate (35234-88-9) + 6,6-diethylfulvene (7301-16-8)

Guidance literature:

In chloroform-d1; at 25 ℃; Further Variations:; Temperatures; Equilibrium constant;

DOI:10.1021/ol048065k

Reference yield: 97.0%

6,6-diethylfulvene (7301-16-8) + C16H11FO3 → (5aS,8aR,9R)-9-((E)-4-fluorostyryl)-8-(pentan-3-ylidene)-5a,8,8a,9-tetrahydrocyclopenta[b][1,3]dioxolo[4,5-g]chromene

Guidance literature:

C₁₆H₁₁FO₃; With C₃₃H₅₂N₄O₄; scandium tris(trifluoromethanesulfonate); In ethyl acetate; at 25 ℃; for 0.5h;

6,6-diethylfulvene; In ethyl acetate; at 0 ℃; for 48h; enantioselective reaction;

DOI:10.1039/c7cc08124c

Reference yield: 95.0%

6,6-diethylfulvene (7301-16-8) + N′-(2-bromo-1-phenylethylidene)benzohydrazide → (4aS,7aR)-(5-(pentan-3-ylidene)-3-phenyl-4,4a,5,7a-tetrahydro-1H-cyclopenta[c]pyridazin-1-yl)(phenyl)methanone

Guidance literature:

With copper(I) triflate benzene complex; sodium carbonate; 2,2'-isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]; In dichloromethane; at -20 ℃; stereoselective reaction; Inert atmosphere;

DOI:10.1039/c7cc09896k

Downstream raw materials:

TiCl₂(C₅H₄C(C₂H₅)2C₆H₅)(C₅H₄CH₂CH(CH₂)3O)

TiCl₂(C₅H₄C(C₂H₅)2C₆H₄OCH₃)2

TiCl₂(C₅H₅)(C₅H₄C(C₂H₅)2C₆H₄OCH₃)

TiCl₂(C₅H₅)(C₅H₄C(C₂H₅)2C₆H₄OCH₃)

Refernces