Propanoic acid, 2,2-dimethyl-, silver(1+) salt

Base Information

• Chemical Name: Propanoic acid, 2,2-dimethyl-, silver(1+) salt
• CAS No.: 7324-58-5
• Molecular Formula: C5H10O2.Ag
• Molecular Weight: 208.993
• Mol file: 7324-58-5.mol

Synonyms:silver(I) 2,2-dimethylpropionate;Ag(OCOtBu);Ag(OPiv);silver(I) tert-butylcarboxylate;silver(I) trimethylacetate;AgOPiv;

Chemical Property of Propanoic acid, 2,2-dimethyl-, silver(1+) salt

Chemical Property:

• Melting Point: 240 °C (sublm)
• PSA: 40.13000
• LogP: -0.21760

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Propanoic acid, 2,2-dimethyl-, silver(1+) salt

There total 4 articles about Propanoic acid, 2,2-dimethyl-, silver(1+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

silver (7440-22-4) + Trimethylacetic acid (75-98-9) → silver pivalate (7324-58-5)

Guidance literature:

Trimethylacetic acid; With sodium hydroxide; In water; at 20 ℃; for 0.25h;

silver; With nitric acid; In water; at 20 ℃; for 0.416667h; Darkness;

Reference yield: 88.0%

silver nitrate + Trimethylacetic acid (75-98-9) → silver pivalate (7324-58-5)

Guidance literature:

With NH₃; In water; ligand was suspended in water, stirred with warming, NH3 was added, filtered, AgNO3 in water was added; filtered in air, washed with water, EtOH, Et2O, dried in vacuo for 3 h; elem. anal.;

DOI:10.1016/S0020-1693(01)00718-6

Reference yield: 82.0%

Trimethylacetic acid (75-98-9) → silver pivalate (7324-58-5)

Guidance literature:

With silver(II) oxide; In water; acetonitrile; at 70 ℃; for 1h;

upstream raw materials:

Trimethylacetic acid

silver

Downstream raw materials:

4-methoxyphenyl 2,2-dimethylpropionate

Refernces

• 1、 -. "MANUFACTURING METHOD OF BIPYRIDYL COMPOUND". Paragraph 0080. . Retrieved 2017/09/16.
• 2、 Zhu, Ru-Yi,He, Jian,Wang, Xiao-Chen,Yu, Jin-Quan. "Ligand-promoted alkylation of C(sp3)-H and C(sp2)-H bonds". supporting information. p. 13194 - 13197. Retrieved 2015/03/30.