AKOS BBS-00005656

Base Information

• Chemical Name: AKOS BBS-00005656
• CAS No.: 7345-50-8
• Molecular Formula: C14H15NOS3
• Molecular Weight: 309.47000
• Hs Code.: 2933990090
• Mol file: 7345-50-8.mol

Synonyms:4,4-Dimethyl-1-thiono-8-ethoxy-4,5-dihydro-1H-1,2-dithiolo<3,4-c>chinolin;8-ethoxy-4,5-dihydro-4,4-dimethyl-2,3-dithiolo<3,4-c>quinoline-1-thione;

Chemical Property of AKOS BBS-00005656

Chemical Property:

• PSA: 109.83000
• LogP: 5.40340

Purity/Quality:

98%min ^*data from raw suppliers

8-Ethoxy-4,4-dimethyl-4,5-dihydro-1H-[1,2]dithiolo[3,4-c]quinoline-1-thione ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of AKOS BBS-00005656

There total 2 articles about AKOS BBS-00005656 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ethoxyquin (91-53-2) → 8-ethoxy-4,5-dihydro-4,4-dimethyl-5H-2,3-dithiolo<5,4-c>-quinoline-1-thione (7345-50-8)

Guidance literature:

With sulfur; In N,N-dimethyl-formamide;

DOI:10.1039/j39680001074

Reference yield:

6-ethoxy-2,2,4-trimethyl-1,3-dihydroquinoline (16489-90-0,212186-67-9,212186-69-1) → 8-ethoxy-4,5-dihydro-4,4-dimethyl-5H-2,3-dithiolo<5,4-c>-quinoline-1-thione (7345-50-8)

Guidance literature:

With sulfur; In various solvent(s); Heating; or without solvent, 210-220 deg C, 40-60 min;

DOI:10.1007/BF00953730

Reference yield: 62.0%

oxalyl dichloride (79-37-8) + 8-ethoxy-4,5-dihydro-4,4-dimethyl-5H-2,3-dithiolo<5,4-c>-quinoline-1-thione (7345-50-8) → C16H13NO3S3 (497231-43-3)

Guidance literature:

In toluene; Heating;

DOI:10.1007/s10593-006-0122-2

upstream raw materials:

Ethoxyquin

6-ethoxy-2,2,4-trimethyl-1,3-dihydroquinoline

Downstream raw materials:

C₁₆H₁₃NO₃S₃

(8-ethoxy-4,4-dimethyl-4,5-dihydro-[1,2]dithiolo[3,4-c]quinolin-1-ylidene)-(4-ethoxy-phenyl)-amine

Refernces

• 1、 Shikhaliev, Kh. S.,Kasaikina, O. T.,Shmyreva, Zh. V.. "SULFURATION OF 2,2,4-TRIMETHYL-1,2,3,4-TETRAHYDROQUINOLINES". . p. 176 - 178. Retrieved 2007/10/02.