Silane, triethyl[(1Z)-2-phenylethenyl]-

Base Information

• Chemical Name: Silane, triethyl[(1Z)-2-phenylethenyl]-
• CAS No.: 75645-33-9
• Molecular Formula: C₁₄H₂₂Si
• Molecular Weight: 218.414
• Mol file: 75645-33-9.mol

Synonyms:

Chemical Property of Silane, triethyl[(1Z)-2-phenylethenyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Silane, triethyl[(1Z)-2-phenylethenyl]-

There total 18 articles about Silane, triethyl[(1Z)-2-phenylethenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

triethylsilane (617-86-7) + phenylacetylene (536-74-3) → (Z)-β-(triethylsilyl)styrene (1206-29-7,21209-32-5,75645-33-9)

Guidance literature:

With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II); In dichloromethane; at 20 ℃; for 6h; Kinetics; Glovebox; Schlenk technique; Inert atmosphere;

DOI:10.1021/om501019j

Reference yield: 96.0%

triethylsilane (617-86-7) + phenylacetylene (536-74-3) → triethylsilylphenylethyne (4131-43-5) + (E)-1-(triethylsilyl)-2-phenylethene (21209-32-5) + 1-(triethylsilyl)styrene (42478-41-1) + (Z)-β-(triethylsilyl)styrene (1206-29-7,21209-32-5,75645-33-9)

Guidance literature:

With triphenylphosphine; dodecacarbonyltetrairidium; In 1,2-dimethoxyethane; at 100 ℃; for 24h; Further Variations:; Reagents; Solvents; Product distribution;

DOI:10.1016/S0040-4039(99)02174-7

Reference yield: 81.0%

triethylsilane (617-86-7) + phenylacetylene (536-74-3) → (E)-1-(triethylsilyl)-2-phenylethene (21209-32-5) + (Z)-β-(triethylsilyl)styrene (1206-29-7,21209-32-5,75645-33-9)

Guidance literature:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; In dichloromethane; at 45 ℃; for 3h;

DOI:10.1021/ol0059697

upstream raw materials:

triethylsilane

phenylacetylene

4-trifluoromethylphenylacetylene

styrene

Downstream raw materials:

C₂₀H₃₄Si

Refernces

• 1、 Atwi, Boshra,Bauer, Matthias,Buchmeiser, Michael R.,Frey, Wolfgang,Nowakowski, Michal,Panyam, Pradeep K. R.,Ziegler, Felix. "Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio- and Stereoselectivity in the Hydrosilylation of Alkynes". supporting information. p. 17220 - 17229. Retrieved 2021/11/10.
• 2、 Lamprecht, Zandria,Malan, Frederick P.,Lotz, Simon,Bezuidenhout, Daniela I.. "Synthesis and structure of thienyl Fischer carbene complexes of PtIIfor application in alkyne hydrosilylation". . p. 6220 - 6230. Retrieved 2021/04/16.