(Z)-5-Undecene

Base Information

• Chemical Name: (Z)-5-Undecene
• CAS No.: 764-96-5
• Deprecated CAS: 32968-73-3
• Molecular Formula: C11H22
• Molecular Weight: 154.296
• UNII: UEB0XNU9V1
• DSSTox Substance ID: DTXSID60874002
• Nikkaji Number: J97.385H
• Wikidata: Q22029773
• Mol file: 764-96-5.mol

Synonyms:(Z)-5-Undecene;cis-5-Undecene;5-Undecene, (Z)-;5-Undecene, (5Z)-;epsilon-cis-Undecene;764-96-5;UNII-UEB0XNU9V1;UEB0XNU9V1;cis-undec-5-ene;(5Z)-5-Undecene;5-Undecene, cis-;(5Z)-5-Undecene #;.EPSILON.-CIS-UNDECENE;DTXSID60874002;NGCRXXLKJAAUQQ-LUAWRHEFSA-N;Q22029773

Chemical Property of (Z)-5-Undecene

Chemical Property:

• Vapor Pressure: 0.725mmHg at 25°C
• Melting Point: -106.5°C
• Refractive Index: 1.4302
• Boiling Point: 187.71°C (estimate)
• PSA: 0.00000
• Density: 0.7537
• LogP: 4.31310
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 154.172150702
• Heavy Atom Count: 11
• Complexity: 82

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC=CCCCC
• Isomeric SMILES: CCCCC/C=C\CCCC

Technology Process of (Z)-5-Undecene

There total 14 articles about (Z)-5-Undecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(1-Pentyl-hexylidene)-(2-phenyl-aziridin-1-yl)-amine → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + (Z)-undec-5-ene (764-96-5)

Guidance literature:

With lithium diisopropyl amide; In diethyl ether; at 0 ℃; for 4h;

DOI:10.1021/ja951422p

Reference yield: 90.0%

6-undecanol (23708-56-7) + benzoic acid (65-85-0,8013-63-6) → 5-undecene (4941-53-1,764-96-5,764-97-6) + undec-6-yl benzoate (1051938-75-0)

Guidance literature:

With toluene-4-sulfonic acid; at 100 ℃; for 50h;

DOI:10.1016/j.tetlet.2008.06.058

Reference yield: 89.0%

6-undecanol (23708-56-7) + phenylpropyolic acid (637-44-5) → undec-6-yl phenylpropiolate + 5-undecene (4941-53-1,764-96-5,764-97-6)

Guidance literature:

With dimesitylammonium pentafluorobenzenesulfonate; In n-heptane; at 80 ℃; for 48h;

DOI:10.1021/ja050223v

upstream raw materials:

6-undecanol

4-Phenylbutyric acid

phenylpropyolic acid

benzoic acid

Downstream raw materials:

α-n-pentylheptanoic acid

2-butyloctanoic acid

Refernces

• 1、 Tanemura, Kiyoshi,Suzuki, Tsuneo. "Sulfonated polypyrene (S-PPR) as efficient catalyst for esterification of carboxylic acids with equimolar amounts of alcohols without removing water". . p. 1972 - 1975. Retrieved 2013/04/23.
• 2、 Adams, An,Kitryte, Vaida,Venskutonis, Rimantas,De Kimpe, Norbert. "Model studies on the pattern of volatiles generated in mixtures of amino acids, lipid-oxidation-derived aldehydes, and glucose". . p. 1449 - 1456. Retrieved 2011/10/05.