tert-Butyl vinyl ether

Base Information

• Chemical Name: tert-Butyl vinyl ether
• CAS No.: 926-02-3
• Deprecated CAS: 2056117-93-0
• Molecular Formula: C6H12O
• Molecular Weight: 100.161
• Hs Code.: 29091990
• DSSTox Substance ID: DTXSID0061290
• Nikkaji Number: J421.544C
• Wikidata: Q29448631
• Mol file: 926-02-3.mol

Synonyms:tert-Butyl vinyl ether;926-02-3;2-ethenoxy-2-methylpropane;2-(Ethenyloxy)-2-methylpropane;TERT-BUTYLVINYLETHER;Propane, 2-(ethenyloxy)-2-methyl-;Propane,2-(ethenyloxy)-2-methyl-;vinyl tertiary-butyl ether;2-methyl-2-(vinyloxy)propane;t-butyl vinyl ether;MFCD00048246;tert-butylvinyl ether;Ether, tert-butyl vinyl;tertiarybutyl vinyl ether;tertiary butyl vinyl ether;SCHEMBL49310;2-Methyl-2-vinyloxy-propane;tert-Butyl vinyl ether, 98%;DTXSID0061290;Propano, 2-(eteniloxi)-2-metil-;AKOS009156422;AS-31067;FT-0633103;EN300-117591;Q29448631

Chemical Property of tert-Butyl vinyl ether

Chemical Property:

• Appearance/Colour: liquid
• Vapor Pressure: 117mmHg at 25°C
• Melting Point: 75-76 °C(lit.)
• Refractive Index: n20/D 1.398(lit.)
• Boiling Point: 75 °C at 760 mmHg
• Flash Point: -17oC (closedoCup)
• PSA: 9.23000
• Density: 0.775 g/cm³
• LogP: 1.94500
• Storage Temp.: Refrigerator (+4°C) + Flammables area
• Water Solubility.: Miscible with alcohol, carbon disulfide, chloroform and diethyl ether. Slightly miscible with water.
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 100.088815002
• Heavy Atom Count: 7
• Complexity: 59.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

tert-Butyl vinyl ether 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi; F
• Hazard Codes: F,Xi
• Statements: 11-38
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)(C)OC=C
• Uses: tert-Butyl vinyl ether is used in the synthesis of 3-tert-Butoxycyclobutanone by reacting with ketene using zinc(II) chloride as a catalyst. It acts as an intermediate for the functional vinyl monomer.

Technology Process of tert-Butyl vinyl ether

There total 10 articles about tert-Butyl vinyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-chloroetyl vinyl ether (110-75-8) + tert-butyl alcohol (75-65-0) → tert-butyl vinyl ether (926-02-3)

Guidance literature:

With mercury(II) diacetate;

DOI:10.1021/jo00193a034

Reference yield: 89.1%

→ tert-butyl vinyl ether (926-02-3)

Guidance literature:

Reference yield:

-butyl vinyl ether (111-34-2,92680-80-3) + tert-butyl alcohol (75-65-0) → tert-butyl vinyl ether (926-02-3)

Guidance literature:

DOI:10.1021/jo00408a010

upstream raw materials:

acetaldehyde-(tert-butyl-phenyl-acetal)

diethylene glycol dimethyl ether

potassium tert-butylate

acetylene

Downstream raw materials:

(+/-)-trans-2-tert-butoxy-cyclopropanecarboxylic acid methyl ester

3-[(1,1-dimethylethyl)oxy]cyclobutanone

2-bromo-1-tert-butoxy-1-ethoxyethane

N,N'-bis(2-bromocyclohexyl)-2,5-piperadinedione

Refernces

• 1、 Hodgson, David M.,Bray, Christopher D.,Kindon, Nicholas D.,Reynolds, Nigel J.,Coote, Steven J.,Um, Joann M.,Houk. "Synthesis and C-alkylation of hindered aldehyde enamines". body text. p. 1019 - 1028. Retrieved 2009/07/04.
• 2、 -. "Method for producing alkenyl ethers". . . Retrieved 2008/06/13.