5-Iodo-1-pentene

Base Information

• Chemical Name: 5-Iodo-1-pentene
• CAS No.: 7766-48-5
• Molecular Formula: C5H9I
• Molecular Weight: 196.031
• European Community (EC) Number: 841-855-7
• DSSTox Substance ID: DTXSID70450851
• Nikkaji Number: J794.134J
• Wikidata: Q72484270
• Mol file: 7766-48-5.mol

Synonyms:5-IODO-1-PENTENE;5-iodopent-1-ene;7766-48-5;1-Pentene, 5-iodo-;4-pentenyl iodide;1-iodo-4-pentene;SCHEMBL757691;DTXSID70450851;GTEUBQCAVFVWBL-UHFFFAOYSA-N;GEO-04041;MFCD19688471;AKOS014114620;GS-0692;5-Iodo-1-pentene - Stabilized over Cu;CS-0135974;FT-0758493;E81681;EN300-211547

Chemical Property of 5-Iodo-1-pentene

Chemical Property:

• Refractive Index: 1.5162
• Boiling Point: 142 oC
• Flash Point: 44 oC
• PSA: 0.00000
• Density: .568
• LogP: 2.38760
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 195.97490
• Heavy Atom Count: 6
• Complexity: 32.9

Purity/Quality:

98% ^*data from raw suppliers

5-Iodo-1-pentene - Stabilized over Cu ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCCI

Technology Process of 5-Iodo-1-pentene

There total 6 articles about 5-Iodo-1-pentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

bromopentene (1119-51-3) → 1-iodo-4-pentene (7766-48-5)

Guidance literature:

With sodium iodide; In acetone; at 60 ℃; for 2h;

DOI:10.1021/jo026702j

Reference yield: 83.0%

n-Pent-4-enyl alcohol (821-09-0) → 1-iodo-4-pentene (7766-48-5)

Guidance literature:

With 1H-imidazole; iodine; triphenylphosphine; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1021/ja8026168

Reference yield:

toluene-4-sulfonic acid pent-4-enyl ester (19300-54-0) → 1-iodo-4-pentene (7766-48-5)

Guidance literature:

With sodium iodide; In acetone;

DOI:10.1021/jo00037a019

upstream raw materials:

5-chloropent-1-ene

cyclobutylmethyl iodide

bromopentene

toluene-4-sulfonic acid pent-4-enyl ester

Downstream raw materials:

7-Benzenesulfonyl-7-pent-4-enyl-bicyclo[4.2.0]octa-1,3,5-triene

Dimethyl-5,5-(penten-4-yl)-2-cyclohexandion-1,3

2-methyl-1-phenylhept-6-en-1-one

2-(4-Pentenyl)-4-(phenylthio)-3-sulfolene

Refernces

• 1、 Wrobel, Matthias N.,Margaretha, Paul. "Photocycloisomerization of Boc-protected 5-alkenyl-2,5-dihydro-1H-pyrrol-2-ones". . p. 515 - 521. Retrieved 2003.
• 2、 Li, Bo,Zhang, Jie,Xu, Yongjuan,Yang, Xiaoxiao,Li, Li. "Improved synthesis of unnatural amino acids for peptide stapling". supporting information. p. 2374 - 2377. Retrieved 2017/05/29.
• 3、 Itoh, Taisuke,Shimizu, Yohei,Kanai, Motomu. "Ligand-Enabled, Copper-Catalyzed Regio- and Stereoselective Synthesis of Trialkylsubstituted Alkenylboronates from Unactivated Internal Alkynes". supporting information. p. 7528 - 7531. Retrieved 2016/07/06.