Iron,bis[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-m-oxodi- (9CI)

Base Information

• Chemical Name: Iron,bis[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-m-oxodi- (9CI)
• CAS No.: 18601-34-8
• Molecular Formula: C32H28 Fe2 N4 O5
• Molecular Weight: 660.292
• Mol file: 18601-34-8.mol

Synonyms:Bis[[a,a'-(ethylenedinitrilo)di-o-cresolato(2-)]iron] oxide (7CI); Iron, bis[[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-m-oxodi-; Iron, bis[[a,a'-(ethylenedinitrilo)di-o-cresolato](2-)]-m-oxodi- (8CI); Bis(N,N'-ethylenebis(salicylideneaminato))oxodiiron; Oxobis[bis(salicylidene)ethylenediaminato]diiron; m-Oxobis[N,N'-ethylene[salicylidenimino(2-)]]diiron; m-Oxobis[bis(salicylidene)ethylenediaminato(2-)]diiron

Chemical Property of Iron,bis[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-m-oxodi- (9CI)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iron,bis[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-m-oxodi- (9CI)

There total 35 articles about Iron,bis[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-m-oxodi- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

iron (7439-89-6) + N,N'-ethylenebis(salicylideneimine) (94-93-9) → (μ-oxo)bis[(1,2-ethanediamino-N,N'-bis(salicylidene))iron(III)] (18601-34-8)

Guidance literature:

In acetonitrile; at 20 ℃; for 1.3h; Electrochemical reaction; Inert atmosphere;

DOI:10.1021/acs.oprd.0c00091

Reference yield: 98.5%

N,N'-ethylenebis(salicylideneiminato)iron(II) (578710-63-1,14167-12-5) + Nitrosobenzene (586-96-9) → (μ-oxo)bis[(1,2-ethanediamino-N,N'-bis(salicylidene))iron(III)] (18601-34-8) + Azobenzene (1227476-15-4) + azoxybenzene (495-48-7,55599-32-1)

Guidance literature:

With sodium tetraphenyl borate; In tetrahydrofuran; To a filtered soln. obtained from complex, NaBPh4 and THF was added nitrosobenzene in THF in 40 min, stirred for 2 h (N2 atm.);; filtered;;

DOI:10.1039/DT9840002577

Reference yield: 98.0%

chloro(N,N'-ethylenebis(salicylideneiminato))iron(III) (16649-19-7,38586-93-5) + bis(triphenylphosphoranylidene)ammonium nitrite → (μ-oxo)bis[(1,2-ethanediamino-N,N'-bis(salicylidene))iron(III)] (18601-34-8) + nitrogen(II) oxide (10102-43-9)

Guidance literature:

In acetonitrile; under vac., equimolar mixt.; chromy.;

DOI:10.1016/S0277-5387(00)00662-8

upstream raw materials:

chloro(N,N'-ethylenebis(salicylideneiminato))iron(III)

(N,N'-ethylenebis(salicylideneiminato))iron(III) nitrate

sodium nitrite

silver(I) nitrite

Downstream raw materials:

Fe(C₆H₄OCHNCH₂CH₂NCHC₆H₄O)C₆H₄O₂H

Fe⁽³⁺⁾*(OC₆H₄CHNCH₂)2^(2-)*C₆H₅CO₂^(1-)=[Fe((OC₆H₄CHNCH₂)2)(OCOC₆H₅)]

[Fe(salen)(1,2,4-triazole^(1-))]n

deferoxamine iron(III) complex

Refernces

• 1、 Bourne, Richard A.,Kapur, Nikil,Nicholls, Thomas P.,Schotten, Christiane,Stephen, Hamish R.,Willans, Charlotte E.,Woodward, Madeleine. "A Versatile Electrochemical Batch Reactor for Synthetic Organic and Inorganic Transformations and Analytical Electrochemistry". . p. 1084 - 1089. Retrieved 2020.
• 2、 Carre, B.,Costes, J.-P.,Tommasino, J.-B.,Montauzon, D. de,Soulet, F.,Fabre, P.-L.. "". . p. 641 - 650. Retrieved 1993.
• 3、 -. "PROCESS FOR PRODUCING ESTER". Paragraph 0095. . Retrieved 2018/08/02.
• 4、 -. "TRANSESTERIFICATION REACTION BY MEANS OF IRON CATALYST". Paragraph 0114; 0115. . Retrieved 2017/10/10.