cis-4-Octene

Base Information

• Chemical Name: cis-4-Octene
• CAS No.: 7642-15-1
• Molecular Formula: C8H16
• Molecular Weight: 112.215
• European Community (EC) Number: 231-578-4
• UNII: 19430WHF5E
• DSSTox Substance ID: DTXSID50872996
• Nikkaji Number: J87.936C
• Wikidata: Q27252062
• Mol file: 7642-15-1.mol

Synonyms:cis-4-Octene;7642-15-1;(Z)-Oct-4-ene;(Z)-4-Octene;4-Octene, (Z)-;(4Z)-4-Octene;4-Octene, (4Z)-;UNII-19430WHF5E;19430WHF5E;EINECS 231-578-4;MFCD00067484;4-OCTENE, CIS-;.DELTA.-CIS-OCTENE;DTXSID50872996;AKOS006227964;(Z)-4-C8H16;O0135;Q27252062

Chemical Property of cis-4-Octene

Chemical Property:

• Vapor Pressure: 17.9mmHg at 25°C
• Melting Point: -118.7°C
• Refractive Index: 1.4130-1.4170
• Boiling Point: 122°C
• Flash Point: 17°C
• PSA: 0.00000
• Density: 0,72 g/cm3
• LogP: 3.14280
• Water Solubility.: Immiscible with water.
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 112.125200510
• Heavy Atom Count: 8
• Complexity: 45.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

cis-4-Octene ^*data from reagent suppliers

Safty Information:

• Statements: 11
• Safety Statements: 16-33

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCC=CCCC
• Isomeric SMILES: CCC/C=C\CCC
• Uses: cis-4-octene is used as a chain transfer agent in polymerization reactions, and as a depolymerizing agent in epoxy-functionalized oligomers.

Technology Process of cis-4-Octene

There total 151 articles about cis-4-Octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.41%

1-methoxyoctane (929-56-6) → methanol (67-56-1) + trans-4-Octene (14850-23-8) + oct-3-ene (14850-22-7,14919-01-8,138663-42-0,592-98-3) + cis-2-octene (7642-04-8) + trans-2-Octene (13389-42-9) + Dimethyl ether (115-10-6,157621-61-9) + oct-1-ene (111-66-0,25068-25-1) + (Z)-oct-4-ene (7642-15-1)

Guidance literature:

at 350 ℃; under 750.075 Torr; Product distribution / selectivity; Gas phase;

Reference yield: 10.5%

oct-1-ene (111-66-0,25068-25-1) → trans-4-Octene (14850-23-8) + cis-3-octene (14850-22-7) + (E)-3-octene (14919-01-8) + cis-2-octene (7642-04-8) + trans-2-Octene (13389-42-9) + (Z)-oct-4-ene (7642-15-1)

Guidance literature:

With diethylaluminium chloride; nickel diacetate;

DOI:10.1039/c5dt00955c

Reference yield: 2.5%

octane (111-65-9) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 4-octene (592-99-4,7642-15-1,14850-23-8) + oct-3-ene (14850-22-7,14919-01-8,138663-42-0,592-98-3) + cis-2-octene (7642-04-8) + trans-2-Octene (13389-42-9) + oct-1-ene (111-66-0,25068-25-1) + o-xylene (95-47-6) + ethylbenzene (100-41-4,27536-89-6)

Guidance literature:

With V₂O₅-MnO (15percent V₂O₅); air; N₂; at 450 ℃; Gas phase; Continuous flow fixed bed reactor;

DOI:10.1016/j.apcata.2009.11.004

upstream raw materials:

dl-4,5-dibromooctane

(E)-4-Chloro-4-octene

4-Octyne

(4R*,5S*)-4,5-epoxyoctane

Downstream raw materials:

1-penten

acetoxy-1 octene-4

diacetoxy-1,8 octene-4

5-nonen-2-one

Refernces

• 1、 Chum,Wilson. "". . p. 15. Retrieved 1976.
• 2、 Moran, Maria Jesus,Martina, Katia,Bieliunas, Vidmantas,Baricco, Francesca,Tagliapietra, Silvia,Berlier, Gloria,De Borggraeve, Wim M.,Cravotto, Giancarlo. "Copper(0) nanoparticle catalyzed Z-Selective Transfer Semihydrogenation of Internal Alkynes". supporting information. p. 2850 - 2860. Retrieved 2021/05/06.
• 3、 Fudo, Eri,Imai, Shota,Kojima, Yasumi,Kominami, Hiroshi,Tanaka, Atsuhiro. "Controlling the performance of a silver co-catalyst by a palladium core in TiO2-photocatalyzed alkyne semihydrogenation and H2 production". . . Retrieved 2021/08/24.