Phosphine imide, N-chloro-P,P,P-triphenyl-

Base Information

• Chemical Name: Phosphine imide, N-chloro-P,P,P-triphenyl-
• CAS No.: 80166-23-0
• Molecular Formula: C18H15ClNP
• Molecular Weight: 311.751
• Mol file: 80166-23-0.mol

Synonyms:

Chemical Property of Phosphine imide, N-chloro-P,P,P-triphenyl-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphine imide, N-chloro-P,P,P-triphenyl-

There total 1 articles about Phosphine imide, N-chloro-P,P,P-triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ N-chlorotriphenylphosphoraneimine (80166-23-0)

Guidance literature:

Triphenylphosphinimin, Chlor (Bzl.);

DOI:10.1002/zaac.19633200103

Reference yield: 99.0%

N-chlorotriphenylphosphoraneimine (80166-23-0) + triphenylantimony (603-36-1) → triphenylphosphinimino-triphenylstibonium chloride

Guidance literature:

In dichloromethane; with exclusion of moisture, 1 equiv. of P-compd. in CH2Cl2 was added dropwise to CH2Cl2 soln. of Sb-compd.; soln. was concd. in dry N2-stream, several days at room temp., crystals were filtered off, filtrate was evapd. to dryness;

DOI:10.1002/zaac.200400058

Reference yield: 80.0%

N-chlorotriphenylphosphoraneimine (80166-23-0) + acetonitrile (75-05-8,26809-02-9) + tin(ll) chloride → 4H2NP(C6H5)3(1+)*4CH3CN*2SnCl6(2-)=[(H2NP(C6H5)3)4(CH3CN)4(SnCl6)]SnCl6

Guidance literature:

In dichloromethane; acetonitrile; byproducts: [SnCl3(NP(C6H5)3)3]; SnCl2 and ClNPPh3 in CH2Cl2, filtration of the SnCl3(NP(C6H5)3)3 , vac. evapn., redissolving in CH3CN/CH2Cl2, 12 h stirring; filtration, evapn. in flowing N2, elem. anal.;

DOI:10.1002/zaac.200400525