Benzene, 1,1',1''-[[3-(octadecyloxy)-2-(phenylmethoxy)propoxy]methylidyne]tris-, (R)-

Base Information Edit

Chemical Name:Benzene, 1,1',1''-[[3-(octadecyloxy)-2-(phenylmethoxy)propoxy]methylidyne]tris-, (R)-
CAS No.:80459-30-9
Molecular Formula:C47H64O3
Molecular Weight:677.023
Hs Code.:
Mol file:80459-30-9.mol

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1,1',1''-[[3-(octadecyloxy)-2-(phenylmethoxy)propoxy]methylidyne]tris-, (R)- Edit

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzene, 1,1',1''-[[3-(octadecyloxy)-2-(phenylmethoxy)propoxy]methylidyne]tris-, (R)-

There total 18 articles about Benzene, 1,1',1''-[[3-(octadecyloxy)-2-(phenylmethoxy)propoxy]methylidyne]tris-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.6%

: 38169-74-3
1-O-Octadecyl-3-O-trityl-sn-glycerin

: 100-44-7
benzyl chloride

: 80459-30-9
2-O-Benzyl-1-O-octadecyl-3-O-trityl-sn-glycerin

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 80 ℃; for 2h;
DOI:10.1002/hlca.19820650339

Reference yield:

: 83526-54-9
3-O-Octadecyl-1-O-p-toluolsulfonyl-sn-glycerin

: 80459-30-9
2-O-Benzyl-1-O-octadecyl-3-O-trityl-sn-glycerin

Guidance literature:: Multi-step reaction with 13 steps

1: toluene / 1 h / 80 °C

2: pyridine / CHCl₃ / Ambient temperature

3: H₂ / 5percent Pd/C / tetrahydrofuran / Ambient temperature

4: phosphorus oxychloride, Et₃N, pyridine / CHCl₃ / Ambient temperature

5: 66 percent / LiAlH₄ / tetrahydrofuran / Ambient temperature

6: 81 percent / pyridine / Ambient temperature

7: 99 percent / pyridine / CHCl₃ / Ambient temperature

8: 81.5 percent / 1N HCl / dioxane / 1 h / Heating

9: t-BuOK / tetrahydrofuran / Ambient temperature

10: dimethylformamide / 80 °C

11: H₂ / 5percent Pd/C / tetrahydrofuran / 0.25 h

12: 68.7 percent / pyridine / 72 h / Ambient temperature

13: 98.6 percent / NaH / dimethylformamide / 2 h / 80 °C

With pyridine; hydrogenchloride; lithium aluminium tetrahydride; potassium tert-butylate; hydrogen; sodium hydride; triethylamine; trichlorophosphate; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; chloroform; N,N-dimethyl-formamide; toluene;
DOI:10.1002/hlca.19820650339

Reference yield:

: 10567-22-3
(R)-octadecylglycerol

: 80459-30-9
2-O-Benzyl-1-O-octadecyl-3-O-trityl-sn-glycerin

Guidance literature:: Multi-step reaction with 8 steps

1: 81 percent / pyridine / Ambient temperature

2: 99 percent / pyridine / CHCl₃ / Ambient temperature

3: 81.5 percent / 1N HCl / dioxane / 1 h / Heating

4: t-BuOK / tetrahydrofuran / Ambient temperature

5: dimethylformamide / 80 °C

6: H₂ / 5percent Pd/C / tetrahydrofuran / 0.25 h

7: 68.7 percent / pyridine / 72 h / Ambient temperature

8: 98.6 percent / NaH / dimethylformamide / 2 h / 80 °C

With pyridine; hydrogenchloride; potassium tert-butylate; hydrogen; sodium hydride; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; chloroform; N,N-dimethyl-formamide;
DOI:10.1002/hlca.19820650339