Triphenyl(1-phenylethenyl)silane

Base Information

• Chemical Name: Triphenyl(1-phenylethenyl)silane
• CAS No.: 804-83-1
• Molecular Formula: C26H22Si
• Molecular Weight: 362.546
• DSSTox Substance ID: DTXSID70553558
• Nikkaji Number: J1.464.632I
• Wikidata: Q82434168
• Mol file: 804-83-1.mol

Synonyms:Silane, triphenyl(1-phenylethenyl)-;804-83-1;Triphenyl(1-phenylethenyl)silane;DTXSID70553558

Chemical Property of Triphenyl(1-phenylethenyl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 362.149077236
• Heavy Atom Count: 27
• Complexity: 411

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C(C1=CC=CC=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Triphenyl(1-phenylethenyl)silane

There total 9 articles about Triphenyl(1-phenylethenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

phenylacetylene (536-74-3) + HSiPh3 (789-25-3) → (E)-1-(triphenylsilyl)-2-phenylethene (804-83-1)

Guidance literature:

With platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane; tri-tert-butyl phosphine; In tetrahydrofuran; at 20 ℃; regioselective reaction; Inert atmosphere;

DOI:10.1016/j.cclet.2009.11.040

Reference yield: 30.0%

isobutyl vinyl ether (109-53-5,9003-44-5) + thiobenzoyltriphenylsilane (79841-57-9) → (E)-1-(triphenylsilyl)-2-phenylethene (804-83-1)

Guidance literature:

at -70 ℃; for 4h; Irradiation;

Reference yield: 27.0%

phenylacetylene (536-74-3) + HSiPh3 (789-25-3) → (E)-1-(triphenylsilyl)-2-phenylethene (804-83-1) + (E)-1-triphenylsilyl-2-phenylethene (33105-34-9)

Guidance literature:

With dichloro(ethylenediamine)-platinum(II); In neat (no solvent); at 90 ℃; for 18h; stereoselective reaction; Inert atmosphere;

DOI:10.1016/j.tetlet.2020.152300

upstream raw materials:

1-phenyl-1-triphenylsilanyl-ethanol

phenylacetylene

HSiPh₃

(1,2-epoxyethyl)triphenylsilane

Downstream raw materials:

(E)-1,2-diphenyl-ethene

Refernces

• 1、 Fotie, Jean,Enechojo Agbo, Mercy,Qu, Fengrui,Tolar, Trevor. "Dichloro(ethylenediamine)platinum(II), a water-soluble analog of the antitumor cisplatin, as a heterogeneous catalyst for a stereoselective hydrosilylation of alkynes under neat conditions". supporting information. . Retrieved 2020/08/13.
• 2、 Lu, Chunxin,Gu, Shaojin,Chen, Wanzhi,Qiu, Huayu. "Platinum(ii) complexes with polydentate N-heterocyclic carbenes: Synthesis, structural characterization and hydrosilylation catalysis". experimental part. p. 4198 - 4204. Retrieved 2010/07/09.