1,1,2,2,3,3-Hexakis(2,6-dimethylphenyl)trisilirane

Base Information

• Chemical Name: 1,1,2,2,3,3-Hexakis(2,6-dimethylphenyl)trisilirane
• CAS No.: 80584-59-4
• Molecular Formula: C48H54Si3
• Molecular Weight: 715.213
• DSSTox Substance ID: DTXSID20413613
• Wikidata: Q82221862
• Mol file: 80584-59-4.mol

Synonyms:1,1,2,2,3,3-hexakis(2,6-dimethylphenyl)trisilirane;80584-59-4;Cyclotrisilane, hexakis(2,6-dimethylphenyl)-;DTXSID20413613;hexa(2,6-dimethylphenyl)cyclotrisilane

Chemical Property of 1,1,2,2,3,3-Hexakis(2,6-dimethylphenyl)trisilirane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 714.35333133
• Heavy Atom Count: 51
• Complexity: 886

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=C(C(=CC=C1)C)[Si]2([Si]([Si]2(C3=C(C=CC=C3C)C)C4=C(C=CC=C4C)C)(C5=C(C=CC=C5C)C)C6=C(C=CC=C6C)C)C7=C(C=CC=C7C)C

Technology Process of 1,1,2,2,3,3-Hexakis(2,6-dimethylphenyl)trisilirane

There total 1 articles about 1,1,2,2,3,3-Hexakis(2,6-dimethylphenyl)trisilirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

bis(2,6-dimethylphenyl)dichlorosilane (80584-60-7) → tetrakis-1,1,2,2-(2,6-dimethylphenyl)disilane (80593-68-6) + 1,1,2,2,3,3-Hexakis-(2,6-dimethyl-phenyl)-trisilirane (80584-59-4)

Guidance literature:

With naphthalen-1-yl-lithium; In 1,2-dimethoxyethane; at -78 ℃; for 1h;

DOI:10.1021/ja00368a065

Reference yield:

1,1,2,2,3,3-Hexakis-(2,6-dimethyl-phenyl)-trisilirane (80584-59-4) → 1,2-Dibromo-1,1,2,2-tetrakis-(2,6-dimethyl-phenyl)-disilane

Guidance literature:

Multi-step reaction with 2 steps

1: 0.08 h / Ambient temperature; Irradiation

2: Br₂

With bromine;

DOI:10.1021/ja00368a065

Reference yield:

1,1,2,2,3,3-Hexakis-(2,6-dimethyl-phenyl)-trisilirane (80584-59-4) → tetrakis-1,1,2,2-(2,6-dimethylphenyl)disilane (80593-68-6)

Guidance literature:

for 0.0833333h; Ambient temperature; Irradiation;

DOI:10.1021/ja00368a065

upstream raw materials:

bis(2,6-dimethylphenyl)dichlorosilane

Downstream raw materials:

tetrakis-1,1,2,2-(2,6-dimethylphenyl)disilane