Technology Process of Rhenium, trichlorotris(methyldiphenylphosphine)-
There total 8 articles about Rhenium, trichlorotris(methyldiphenylphosphine)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
HCl;
In
ethanol; water;
An aq. soln. of HReO4 and concd. HCl was added to EtOH, then phosphine was added and the mixt. was refluxed 15 min, cooled to 25°C (N2 atm.);; filtered, ppt. was washed with EtOH;;
DOI:10.1021/ja00338a021
- Guidance literature:
-
In
tetrahydrofuran; toluene;
Ar atmosphere, solvent mixt. 1:1, excess of iodine-activated Mg, stirring (100°C, overnight); filtration, concn. in vac., extn. (benzene), filtration, pptn. by addn. of MeOH; elem. anal.;
- Guidance literature:
-
With
HCl;
In
ethanol;
stirring AgReO4, phosphine, HCl and ethanol (reflux), 12h; filtration; extn. of solid (CH2Cl2); reducing volume (vac.); pptn. of ReCl3(phosphine)3; bubbling N2 through soln.; crystn. of oxo compd.; filtration; recrystn. by diffusing pentane into satd. CH2Cl2 soln., -30°C, overnight; elem. anal.;
