Dimethyltin sulfide

Base Information

• Chemical Name: Dimethyltin sulfide
• CAS No.: 13269-74-4
• Molecular Formula: C2H6 S Sn
• Molecular Weight: 180.846
• Hs Code.: 2931900090
• European Community (EC) Number: 236-266-1
• DSSTox Substance ID: DTXSID1065390
• Wikidata: Q81992177
• Mol file: 13269-74-4.mol

Synonyms:Dimethyltin sulfide;13269-74-4;Stannane, dimethylthioxo-;dimethyl(sulfanylidene)tin;Dimethylthioxostannane;EINECS 236-266-1;Dimethyl tin sulfide;dimethylstannanethione;C2H6SSn;C2-H6-S-Sn;SCHEMBL668915;DTXSID1065390;AKOS025293692;FT-0695763;FT-0718858

Chemical Property of Dimethyltin sulfide

Chemical Property:

• Melting Point: 149 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 32.09000
• Density: g/cm³
• LogP: 1.43500
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 181.921224
• Heavy Atom Count: 4
• Complexity: 29

Purity/Quality:

98%Min ^*data from raw suppliers

DIMETHYLTIN SULFIDE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](=S)C

Technology Process of Dimethyltin sulfide

There total 1 articles about Dimethyltin sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

hydrogen sulfide (7783-06-4) + dimethyltin dichloride (753-73-1) → dimethyltin sulfide (13269-74-4)

Guidance literature:

With triethylamine; In tetrahydrofuran; for 2h;

Reference yield: 64.0%

dimethyltin sulfide (13269-74-4) + (2,6-dimethoxyphenyl)lithium (2785-97-9) → bis(2,6-dimethoxyphenyl)dimethyltin (142599-76-6)

Guidance literature:

In diethyl ether; suspension of Li-compd. (prepared form C6H4(OCH3)2, 15% hexane soln. of BuLi and TMEDA under Ar, at room temp for 1-2) added to suspension of Sn-compd. under Ar, stirred at room temp. for 5 h; washed (H2O), evapd. (vac.), recrystd. (MeOH);

DOI:10.1246/bcsj.65.1389

upstream raw materials:

hydrogen sulfide

dimethyltin dichloride

Downstream raw materials:

bis(2,6-dimethoxyphenyl)dimethyltin

Refernces