Bis(tetrabutylammonium) sulphate

Base Information

• Chemical Name: Bis(tetrabutylammonium) sulphate
• CAS No.: 2472-88-0
• Molecular Formula: C32H72N2O4S
• Molecular Weight: 581.001
• Hs Code.: 2923900090
• European Community (EC) Number: 219-593-4
• UNII: BY5NUA8V2A
• DSSTox Substance ID: DTXSID70179454
• Mol file: 2472-88-0.mol

Synonyms:Bu(4)NBr;tetra-n-butylammonium dodecylsulfate;tetra-n-butylammonium hexafluorophosphate;tetrabutylammonium;tetrabutylammonium azide;tetrabutylammonium bromide;tetrabutylammonium chloride;tetrabutylammonium cyanide;tetrabutylammonium fluoride;tetrabutylammonium hydrogen sulfate;tetrabutylammonium hydroxide;tetrabutylammonium iodide;tetrabutylammonium monophosphate;tetrabutylammonium nitrate;tetrabutylammonium perchlorate;tetrabutylammonium sulfate;tetrabutylammonium sulfate (1:1), sodium salt

Chemical Property of Bis(tetrabutylammonium) sulphate

Chemical Property:

• Appearance/Colour: White powder
• Refractive Index: n20/D 1.417
• Boiling Point: 84 °C
• PSA: 88.64000
• Density: 1.01 g/mL at 25 °C
• LogP: 9.75000
• Solubility.: Fully miscible.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 24
• Exact Mass: 580.52127996
• Heavy Atom Count: 39
• Complexity: 178

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetra-n-butylammonium sulfate, 50% in water ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.[O-]S(=O)(=O)[O-]
• Uses: Tetrabutylammonium Sulfate as catalysts in the polymerization of methyl methacrylate by electrolysis.

Technology Process of Bis(tetrabutylammonium) sulphate

There total 5 articles about Bis(tetrabutylammonium) sulphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetra(n-butyl)ammonium hydroxide (2052-49-5) → tetrabutylammonium sulfate (2472-88-0)

Guidance literature:

With sulfuric acid;

DOI:10.1021/ol100776x

Reference yield:

tetra-(n-butyl)ammonium iodide (311-28-4) → tetrabutylammonium sulfate (2472-88-0)

Guidance literature:

With thallium(I) sulfate; In water; for 16h;

DOI:10.1021/ja00196a037

Reference yield:

tetra(n-butyl)ammonium hydroxide (2052-49-5) + tetra(n-butyl)ammonium hydrogensulfate (32503-27-8) → tetrabutylammonium sulfate (2472-88-0)

Guidance literature:

In methanol;

DOI:10.1016/j.tet.2013.07.051

upstream raw materials:

tetra-(n-butyl)ammonium iodide

tetra(n-butyl)ammonium hydroxide

tetra(n-butyl)ammonium hydrogensulfate

Downstream raw materials:

2-amino-5-[[[5-(1,1-dimethylethyl)-2-oxazolyl]methyl]thio]-thiazole

2-([{2-[(2,6-dichlorophenyl)imino]-1-imidazolidinyl}oxy]methyl)pyridine-1-oxide

C₁₆H₃₆N⁽¹⁺⁾*C₂₇H₂₅Br₂N₆⁽¹⁺⁾*O₄S^(2-)

Refernces

• 1、 Brown, Asha,Lang, Thomas,Mullen, Kathleen M.,Beer, Paul D.. "Active metal template synthesis of a neutral indolocarbazole-containing [2]rotaxane host system for selective oxoanion recognition". . p. 4587 - 4594. Retrieved 2017/07/10.
• 2、 Schulze, Benjamin,Friebe, Christian,Hager, Martin D.,Guenther, Wolfgang,Koehn, Uwe,Jahn, Burkhard O.,Goerls, Helmar,Schubert, Ulrich S.. "Anion complexation by triazolium "ligands": Mono- and bis-tridentate complexes of sulfate". supporting information; experimental part. p. 2710 - 2713. Retrieved 2010/09/05.