Dichloro(pentafluorophenyl)borane

Base Information

• Chemical Name: Dichloro(pentafluorophenyl)borane
• CAS No.: 830-48-8
• Molecular Formula: C6BCl2F5
• Molecular Weight: 248.775
• DSSTox Substance ID: DTXSID50504846
• Nikkaji Number: J1.948.481E
• Wikidata: Q82359612
• Mol file: 830-48-8.mol

Synonyms:dichloro(pentafluorophenyl)borane;830-48-8;pentafluorophenyldichloroborane;SCHEMBL339861;DTXSID50504846

Chemical Property of Dichloro(pentafluorophenyl)borane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 247.9390264
• Heavy Atom Count: 14
• Complexity: 191

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C1=C(C(=C(C(=C1F)F)F)F)F)(Cl)Cl

Technology Process of Dichloro(pentafluorophenyl)borane

There total 30 articles about Dichloro(pentafluorophenyl)borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

boron trichloride (10294-34-5) + (pentafluorophenyl)trimethyltin (1015-53-8) → dichloro(pentafluorophenyl)borane (830-48-8)

Guidance literature:

20°C, 24h, sealed tube; vac., trapped at -78°C;

DOI:10.1039/jr9650003933

Reference yield: 91.0%

boron trichloride (10294-34-5) + (pentafluoro phenyl) ethyl mercury → dichloro(pentafluorophenyl)borane (830-48-8)

Guidance literature:

In neat (no solvent); reaction in a closed tube;;

DOI:10.1039/J39670002185

Reference yield: 84.0%

boron trichloride (10294-34-5) + (pentafluoro phenyl) methyl mercury (653-38-3) → dichloro(pentafluorophenyl)borane (830-48-8)

Guidance literature:

In neat (no solvent); reaction in a closed tube;;

DOI:10.1039/jr9650003933

upstream raw materials:

(pentafluorophenyl)trimethyltin

boron trichloride

tributyl(pentafluorophenyl)stannane

(pentafluoro phenyl) methyl mercury

Downstream raw materials:

Pentafluorobenzene

boric acid

bis(pentafluorophenyl)boron chloride

boron trichloride

Refernces

• 1、 Bardin,Prikhod’ko,Shmakov,Shabalin, A. Yu.,Adonin, N. Yu.. "Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates". . p. 50 - 61. Retrieved 2020/04/09.
• 2、 Mewald, Marius,Froehlich, Roland,Oestreich, Martin. "An axially chiral, electron-deficient borane: Synthesis, coordination chemistry, Lewis acidity, and reactivity". supporting information; experimental part. p. 9406 - 9414. Retrieved 2011/10/09.