ALKYLATE225

Base Information

• Chemical Name: ALKYLATE225
• CAS No.: 53570-72-2
• Mol file: 53570-72-2.mol

Synonyms:Alkylate 225

Chemical Property of ALKYLATE225

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ALKYLATE225

There total 24 articles about ALKYLATE225 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2-bromododecane (13187-99-0) + phenylboronic acid (98-80-6) → 2-phenyldodecane (2719-61-1,53570-72-2)

Guidance literature:

With potassium phosphate; bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; bis(N-methylimidazol-2-yl)methane; In N,N-dimethyl acetamide; at 80 ℃; for 2h;

Reference yield: 34.0%

2-bromododecane (13187-99-0) + phenylmagnesium bromide (100-58-3) → dodecane (112-40-3) + 1-dodecene (112-41-4,25067-08-7,62132-67-6) + dodec-2-ene (1652-96-6) + 2-phenyldodecane (2719-61-1,53570-72-2)

Guidance literature:

phenylmagnesium bromide; With vanadium(III) chloride; In tetrahydrofuran; at 20 ℃; for 0.333333h;

2-bromododecane; In tetrahydrofuran; at 25 ℃; for 1h;

DOI:10.1246/bcsj.81.287

Reference yield:

1-chlorododecane (112-52-7) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 1-dodecylbenzene (123-01-3) + 6-phenyldodecane (2719-62-2) + 2-phenyldodecane (2719-61-1,53570-72-2) + (1-butyloctyl)benzene (2719-63-3) + 3-phenyldodecane (2400-00-2) + 4-phenyldodecane (2719-64-4)

Guidance literature:

With 1-butyl-iso-quinolinium hydrogen sulfate; iron(III) chloride; at 60 ℃; for 0.833333h; under 2250.23 Torr; Temperature; Reagent/catalyst; Autoclave; Inert atmosphere;

upstream raw materials:

(+/-)-2-hydroxy-2-phenyl-dodecane

1-dodecene

benzene

1-dodecyl alcohol

Refernces

• 1、 Liu, Meng-Nan,Li, Yu-Zhao,Xie, Zhi-Xia,Hao, Qing-Qing,Luo, Qun-Xing,Zhang, Jianbo,Chen, Huiyong,Dai, Chengyi,Ma, Xiaoxun. "Organosilane surfactant-directed synthesis of hierarchical mordenite with enhanced catalytic performance in the alkylation of benzene with 1-dodecene". . p. 16638 - 16644. Retrieved 2020/10/14.
• 2、 Zhang, Siyi,Li, Junqiao,Ji, Genzhong,Liang, Xuezheng. "One-pot synthesis of a novel magnetic carbon based solid acid for alkylation". . p. 414 - 421. Retrieved 2017/08/08.