2-benzyl-N-methylaniline

Base Information

• Chemical Name: 2-benzyl-N-methylaniline
• CAS No.: 51570-52-6
• Molecular Formula: C14H15N
• Molecular Weight: 197.28
• NSC Number: 165834
• DSSTox Substance ID: DTXSID70304461
• Nikkaji Number: J2.606.388D
• Wikidata: Q82050382
• Mol file: 51570-52-6.mol

Synonyms:2-benzyl-N-methylaniline;51570-52-6;NSC165834;Cambridge id 5102095;Oprea1_164679;SCHEMBL4575540;DTXSID70304461;N-(2-benzylphenyl)-N-methylamine;AKOS000254745;NSC-165834;EN300-23933342

Chemical Property of 2-benzyl-N-methylaniline

Chemical Property:

• Vapor Pressure: 0.000173mmHg at 25°C
• Boiling Point: 329.8°Cat760mmHg
• Flash Point: 161°C
• PSA: 12.03000
• Density: 1.047g/cm³
• LogP: 3.39210
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 197.120449483
• Heavy Atom Count: 15
• Complexity: 172

Purity/Quality:

99%min ^*data from raw suppliers

2-BENZYL-N-METHYLANILINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CNC1=CC=CC=C1CC2=CC=CC=C2

Technology Process of 2-benzyl-N-methylaniline

There total 13 articles about 2-benzyl-N-methylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-methyl-2-(2-phenylethyl)pyridinium iodide (81734-60-3) → o-methylaminodiphenylmethane (51570-52-6)

Guidance literature:

With methylammonium sulfite; methylamine; In water; at 200 ℃; for 12h; sealed ampul;

DOI:10.1007/BF00512816

Reference yield: 86.0%

N-(2-Benzyl-phenyl)-N-methyl-O-propyl-hydroxylamine (119515-90-1) → o-methylaminodiphenylmethane (51570-52-6)

Guidance literature:

W-2 Raney nickel; In ethanol; for 1h; Ambient temperature;

Reference yield: 82.0%

1-methyl-2-(2-phenylethyl)pyridinium iodide (81734-60-3) → o-methylaminodiphenylmethane (51570-52-6) + 2-(2-phenylethyl)pyridine (2116-62-3)

Guidance literature:

With Dimethylammonium sulphite; at 190 - 200 ℃; for 14h; Yields of byproduct given;

DOI:10.1007/BF00512976

upstream raw materials:

N-methyl-N-phenyl-benzenemethanamine

1-methyl-2-(2-phenylethyl)pyridinium iodide

N-(2-Benzyl-phenyl)-N-methyl-O-propyl-hydroxylamine

benzyl bromide

Downstream raw materials:

acridine

2-phenyl-indole

anthracene

2-benzyl-N-methyl-N-(1-methyl-pyrrolidin-3-ylmethyl)-aniline

Refernces

• 1、 Creencia, Evelyn Cuevas,Taguchi, Kei,Horaguchi, Takaaki. "Thermal reactions of N-Alkyl-2-benzylaniline and N-Alkyl-N′-phenyl-o- phenylenediamine: An unusual route to 2-phenylindole and 2-phenylbenzimidazole". . p. 837 - 843. Retrieved 2008/09/21.
• 2、 Aly, Morsy M.,Badr, Mahmoud Zarif A.,Fahmy, Attiat M.,Mahgoub, Safaa A.. "MOLECULAR REARRANGEMENTS, XVIII. PHOTOLYSIS OF N-ALKYL-ARYLAMINES". . p. 15 - 22. Retrieved 2007/10/02.