silver 2-chlorobenzoate

Base Information

• Chemical Name: silver 2-chlorobenzoate
• CAS No.: 51750-67-5
• Molecular Formula: C7H5ClO2
• Molecular Weight: 263.429
• Mol file: 51750-67-5.mol

Synonyms:

Chemical Property of silver 2-chlorobenzoate

Chemical Property:

• Boiling Point: 275.7°Cat760mmHg
• Flash Point: 120.5°C
• Density: 1.374g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of silver 2-chlorobenzoate

There total 1 articles about silver 2-chlorobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

silver(l) oxide (20667-12-3) + ortho-chlorobenzoic acid (118-91-2) → silver 2-chlorobenzoate (51750-67-5)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 2h; Darkness;

DOI:10.1021/jacs.7b13305

Reference yield: 75.0%

{1,1'-bis(diphenylphosphino)ferrocene} palladium dibromide (124268-93-5) + dichloromethane (75-09-2) + silver 2-chlorobenzoate (51750-67-5) → [Pd(O2C-o-C6H4Cl)2(1,1'-bis(diphenylphosphino)ferrocene)]*0.5CH2Cl2

Guidance literature:

In dichloromethane; (Ar), stirring a soln. of palladium complex and silver salt in CH2Cl2 atroom temp. for 20 h in the dark; filtration through celite column, diffusion through hexane; elem. anal.;

DOI:10.1016/S0022-328X(02)01645-5

Reference yield: 66.0%

silver 2-chlorobenzoate (51750-67-5) + μ-oxy-bis(triphenylantimony) dichloride (1538-63-2,115730-70-6,106436-42-4) → C43H34Cl2O3Sb2

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.14233/ajchem.2021.23045

upstream raw materials:

silver(l) oxide

ortho-chlorobenzoic acid

Downstream raw materials:

chlorobenzene

Refernces

• 1、 Crovak, Robert A.,Hoover, Jessica M.. "A Predictive Model for the Decarboxylation of Silver Benzoate Complexes Relevant to Decarboxylative Coupling Reactions". supporting information. p. 2434 - 2437. Retrieved 2018/02/28.