2-Vinyl-1,3-dioxolane

Base Information

• Chemical Name: 2-Vinyl-1,3-dioxolane
• CAS No.: 3984-22-3
• Molecular Formula: C5H8O2
• Molecular Weight: 100.117
• Hs Code.: 2932999099
• European Community (EC) Number: 223-626-8
• DSSTox Substance ID: DTXSID4073334
• Nikkaji Number: J57.988B
• Wikidata: Q72516359
• Mol file: 3984-22-3.mol

Synonyms:2-Vinyl-1,3-dioxolane;3984-22-3;2-ethenyl-1,3-dioxolane;1,3-Dioxolane, 2-ethenyl-;EINECS 223-626-8;1,3-Dioxolane, 2-vinyl-;Acrolein ethylene acetal;Acrolein-ethylenacetal;2-vinyl-1,3-dioxolan;SCHEMBL305072;DTXSID4073334;2-Vinyl-1,3-dioxolane (VDL);2-Vinyl-1,3-dioxolane, 98%;MFCD00239440;AKOS015912779;LS-62560;FT-0691874

Chemical Property of 2-Vinyl-1,3-dioxolane

Chemical Property:

• Appearance/Colour: Transparent colorless liquid
• Vapor Pressure: 56.5mmHg at 25°C
• Melting Point: 117°C
• Refractive Index: n20/D 1.431
• Boiling Point: 93.3 °C at 760 mmHg
• Flash Point: 21°C
• PSA: 18.46000
• Density: 1.092 g/cm³
• LogP: 0.54530
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 100.052429494
• Heavy Atom Count: 7
• Complexity: 64.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Vinyl-1,3-dioxolane 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,T+
• Hazard Codes: F,T+
• Statements: 11-25-27-36/37/38
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CC1OCCO1

Technology Process of 2-Vinyl-1,3-dioxolane

There total 14 articles about 2-Vinyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

acrolein (107-02-8,25068-14-8) → 2-vinyl-1,3-dioxolane (3984-22-3)

Guidance literature:

In water; ethylene glycol; benzene;

Reference yield: 57.0%

ethylene glycol (107-21-1) + acrolein (107-02-8,25068-14-8) → 2-vinyl-1,3-dioxolane (3984-22-3)

Guidance literature:

pyridinium p-toluenesulfonate; In diethyl ether; pentane; for 95h; Heating;

DOI:10.1021/jo00175a030

Reference yield: 17.0%

acrolein (107-02-8,25068-14-8) + butan-1-ol (71-36-3) → 2-vinyl-1,3-dioxolane (3984-22-3) + 2-<2-(2-hydroxyethoxy)-ethyl>-1,3-dioxolane (83490-15-7) + 1,1,3-tributoxypropane (53963-15-8) + 1,1-dibutoxy-prop-2-en (45094-50-6)

Guidance literature:

With toluene-4-sulfonic acid; ethylene glycol; In dichloromethane; for 5h; Further byproducts given; Heating;

upstream raw materials:

ethylene glycol

acrolein

butan-1-ol

Downstream raw materials:

ethylene glycol monoallyl ether

(E)-4-(2-Hydroxy-ethoxy)-1-phenyl-hexa-1,5-dien-3-ol

4-(2-Hydroxy-ethoxy)-1-phenyl-hex-5-en-3-ol

5-carbethoxy-2H,3H,5H,6H-1,4-dioxocin

Refernces

• 1、 Cheng, Jing,Ji, Ran,Gao, Shi-Juan,Du, Fu-Sheng,Li, Zi-Chen. "Facile synthesis of acid-labile polymers with pendent ortho esters". experimental part. p. 173 - 179. Retrieved 2012/04/23.
• 2、 Nieddu, Enrico,Cataldo, Maurizio,Pinna, Francesco,Strukul, Giorgio. "Acetalization of α,β-unsaturated carbonyl compounds catalyzed by complexes of Pt(II)". . p. 6987 - 6990. Retrieved 2007/10/03.