Vinylidenimine

Base Information

• Chemical Name: Vinylidenimine
• CAS No.: 17619-22-6
• Molecular Formula: C₂H₃N
• Molecular Weight: 41.0525
• Mol file: 17619-22-6.mol

Synonyms:

Chemical Property of Vinylidenimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Vinylidenimine

There total 14 articles about Vinylidenimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

azide vinylique (7570-25-4) → methyl isocyanate (593-75-9,685498-28-6) + 1-ethyleneimine (17619-22-6) + acetonitrile (75-05-8,26809-02-9)

Guidance literature:

at 500 ℃; under 0.001 Torr; Title compound not separated from byproducts;

DOI:10.1016/S0040-4020(01)86146-9

Reference yield:

3-Hydroxypropionitrile (109-78-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1-ethyleneimine (17619-22-6) + acetonitrile (75-05-8,26809-02-9)

Guidance literature:

at 1050 ℃; Title compound not separated from byproducts;

DOI:10.1021/ja00166a011

Reference yield:

3-Hydroxypropionitrile (109-78-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1-ethyleneimine (17619-22-6) + acrylonitrile (107-13-1,25014-41-9) + acetonitrile (75-05-8,26809-02-9)

Guidance literature:

at 800 - 1100 ℃; Product distribution; flash vacuum pyrolysis;

DOI:10.1021/ja00213a002

upstream raw materials:

1,2,4-Triazole

azide vinylique

2-aminonorborn-5-ene

1-tert-Butyl-1,4-dihydro-4-ethenyl-5H-tetrazol-5-on

Downstream raw materials:

N-ethoxycarbonylaziridine

dimethylenecyclourethane

<<4-chloro-6-<(2,3-dimethylphenyl)amino>-2-pyrimidinyl>thio>-N-(2-hydroxyethyl)acetamide

1-(2'-hydroxy-2'-phenylethyl)aziridine

Refernces

• 1、 Maier, Guenther,Eckwert, Juergen,Bothur, Axel,Reisenauer, Hans Peter,Schmidt, Christiane. "Photochemical fragmentation of unsubstituted tetrazole, 1,2,3-Triazole, and 1,2,4-triazole: First matrix-spectroscopic identification of nitrilimine HCNNH". . p. 1041 - 1053. Retrieved 2007/10/03.
• 2、 Dunkin, Ian R.,Shields, Charles J.. "THE PHOTOCHEMISTRY OF 1,4-DIHYDRO-5H-TETRAZOLE DERIVATIVES ISOLATED IN LOW-TEMPERATURE MATRICES". . p. 259 - 268. Retrieved 2007/10/02.