Bromo(butan-2-yl)mercury

Base Information

• Chemical Name: Bromo(butan-2-yl)mercury
• CAS No.: 868-82-6
• Molecular Formula: C₄H₉BrHg
• Molecular Weight: 337.609
• DSSTox Substance ID: DTXSID50499723
• Mol file: 868-82-6.mol

Synonyms:Bromo(butan-2-yl)mercury;s-butylmercury bromide;868-82-6;DTXSID50499723

Chemical Property of Bromo(butan-2-yl)mercury

Chemical Property:

• PSA: 0.00000
• LogP: -1.37790
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 337.95941
• Heavy Atom Count: 6
• Complexity: 30.7

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(C)[Hg]Br

Technology Process of Bromo(butan-2-yl)mercury

There total 2 articles about Bromo(butan-2-yl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bromo-triphenyl-methane (596-43-0) + di-sec-butyl mercury (691-88-3) → triphenylmethyl alcohol (76-84-6) + secondary-butyl mercury(II) bromide (53213-46-0,868-82-6) + sec-butyl triphenylmethyl peroxide (78504-79-7)

Guidance literature:

With oxygen; tetrabutylammomium bromide; In 1,2-dichloro-ethane; benzene; Product distribution; other reaction conditions;

Reference yield: 74.0%

silver tetrafluoroborate (14104-20-2) + di-sec-butyl mercury (691-88-3) + diphenylchloromethane (90-99-3) → 1,1-Diphenylmethanol (91-01-0) + N-(diphenylmethyl)acetamide (5267-35-6) + secondary-butyl mercury(II) bromide (53213-46-0,868-82-6)

Guidance literature:

With potassium bromide; In nitromethane; byproducts: Ph2CH2, Ph2CH(sec-Bu); Ar atmosphere and absence of light and moisture; addn. of AgBF4 in nitromethane to soln. of alkylmercury, portionwise addn. of Ph2CHCl in nitromethane (20°C, TLC monitoring), washing with soln. of KBr; TLC;

DOI:10.1007/BF00955985

Reference yield: 48.0%

triiron dodecarbonyl (17685-52-8) + secondary-butyl mercury(II) bromide (53213-46-0,868-82-6) + thiophenol (108-98-5) → (C2H5(CH3)CHC(O))(C6H5S)Fe2(CO)6

Guidance literature:

With triethylamine; In tetrahydrofuran; addn. of thiol and Et3N to Fe3(CO)12 soln. (equim. amts., room temp., N2-atmosphere), addn. of Hg-compd., stirring (3 h); chromy. (SiO2, pentane);

upstream raw materials:

bromo-triphenyl-methane

di-sec-butyl mercury

silver tetrafluoroborate

diphenylchloromethane

Refernces

• 1、 Uglova, E. V.,Petrovskii, K. B.,Fadeeva, S. S.,Mikhura, I. V.,Reutov, O. A.. "REACTION OF ALKYLMERCURY AND ALKYLTIN COMPOUNDS WITH DIPHENYLMETHYL SALTS". . p. 1231 - 1234. Retrieved 2007/10/02.