2-Methylmyristic acid methyl ester

Base Information

• Chemical Name: 2-Methylmyristic acid methyl ester
• CAS No.: 55554-09-1
• Molecular Formula: C16H32O2
• Molecular Weight: 256.429
• Mol file: 55554-09-1.mol

Synonyms:2-Methylmyristinsaeure-methylester;2-Methyl-tetradecansaeure-methylester;2-methyl-tetradecanoic acid methyl ester;Tetradecanoic acid,2-methyl-,methyl ester;

Chemical Property of 2-Methylmyristic acid methyl ester

Chemical Property:

• Vapor Pressure: 0.0014mmHg at 25°C
• Boiling Point: 296.8°Cat760mmHg
• Flash Point: 134.7°C
• PSA: 26.30000
• Density: 0.864g/cm³
• LogP: 5.10650

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Methylmyristic acid methyl ester

There total 2 articles about 2-Methylmyristic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

methanol (67-56-1) + 1-tetradecene (1120-36-1) + carbon monoxide (201230-82-2) → pentadecanoic acid methyl ester (7132-64-1) + methyl 2-methyltetradecanoate (55554-09-1) + dimethyl 2-dodecylsuccinate (1472-86-2)

Guidance literature:

With oxygen; copper(l) chloride; palladium dichloride; In tetrahydrofuran; at 25 ℃; for 168h; under 760 Torr; Yields of byproduct given;

DOI:10.1246/bcsj.64.3600

Reference yield: 80.0%

methanol (67-56-1) + 1-tetradecene (1120-36-1) + carbon monoxide (201230-82-2) → pentadecanoic acid methyl ester (7132-64-1) + methyl 2-methyltetradecanoate (55554-09-1)

Guidance literature:

With methanesulfonic acid; palladium diacetate; bis(phosphaadamantyl)diphosphine; at 115 ℃;

DOI:10.1039/b103754b

Reference yield:

methyl 2-methyltetradecanoate (55554-09-1) → 2-methylmyristic acid (6683-71-2)

Guidance literature:

With ethanol; sodium hydroxide; at 50 ℃; for 0.25h; Inert atmosphere;

DOI:10.1002/chem.201003176

upstream raw materials:

methanol

1-tetradecene

carbon monoxide

Downstream raw materials:

2-methylmyristic acid

Refernces

• 1、 Amézquita-Valencia, Manuel,Achonduh, George,Alper, Howard. "Pd-Catalyzed Regioselective Alkoxycarbonylation of 1-Alkenes Using a Lewis Acid [SnCl2 or Ti(OiPr)4] and a Phosphine". . p. 6419 - 6424. Retrieved 2015/06/30.
• 2、 Pugh,Drent,Pringle. "Tandem isomerisation-carbonylation catalysis: Highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters". . p. 1476 - 1477. Retrieved 2007/10/03.