Trifluoronitrosomethane

Base Information

• Chemical Name: Trifluoronitrosomethane
• CAS No.: 334-99-6
• Molecular Formula: CF3 N O
• Molecular Weight: 99.0123
• Hs Code.: 2904909090
• European Community (EC) Number: 206-383-2
• UNII: M9H4YRQ7XZ
• DSSTox Substance ID: DTXSID3073896
• Nikkaji Number: J193.766I
• Wikipedia: Trifluoronitrosomethane
• Wikidata: Q2453103
• Mol file: 334-99-6.mol

Synonyms:Trifluoronitrosomethane;334-99-6;trifluoro(nitroso)methane;Methane, trifluoronitroso-;CF3NO;Methane,trifluoronitroso-;Nitrosotrifluoromethane;M9H4YRQ7XZ;EINECS 206-383-2;trifluoronitroso-methane;UNII-M9H4YRQ7XZ;C-F3-N-O;DTXSID3073896;MFCD00042141;AKOS005254914;Q2453103

Chemical Property of Trifluoronitrosomethane

Chemical Property:

• Vapor Pressure: 24900mmHg at 25°C
• Melting Point: -196,6°C
• Boiling Point: -85°C
• Flash Point: °C
• PSA: 29.43000
• Density: 1.54g/cm³
• LogP: 1.27260
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 98.99319811
• Heavy Atom Count: 6
• Complexity: 56.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trifluoronitrosomethane 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 26/27/28
• Safety Statements: 3/7-9-16-36/37/39-38

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(N=O)(F)(F)F
• Uses: Monomer for nitroso rubber.

Technology Process of Trifluoronitrosomethane

There total 43 articles about Trifluoronitrosomethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

bis(trifluoromethyl)cadmium*glyme → trifluoronitrosomethane (334-99-6)

Guidance literature:

With nitrosylchloride;

DOI:10.1016/0022-1139(95)03237-8

Reference yield: 92.0%

(trifluoromethyl)trimethylsilane (81290-20-2) → trifluoronitrosomethane (334-99-6)

Guidance literature:

With nitrosylchloride; cesium fluoride; In 1,2-dimethoxyethane; at -196 - 25 ℃; for 3h;

DOI:10.1039/b205288c

Reference yield: 90.0%

cyanogen chloride (506-77-4) → trifluoronitrosomethane (334-99-6) + hexafluoroazomethane

Guidance literature:

With silver(II) fluoride;

DOI:10.1021/j100450a004

upstream raw materials:

iodotrifluoromethane

cyanogen chloride

trifluoromethyl radical

1-fluoroethylene

Downstream raw materials:

ethyl(trifluoromethyl) ether

Trifluormethanazo-benzol

N-trifluoromethyl-N-2-methylenecyclohexylhydroxylamine

N-trifluoromethyl-N-2-methylcyclohex-2-enylhydroxylamine

Refernces

• 1、 Sibous, Lakhdar,Tipping, Anthony E.. "Fluorinated acetylenes. Part 8. Preparation and some reactions of 5,5,5-trifluoropent-3-yn-2-ol, 5,5,5-trifluoro-1-phenylpent-3-yn-2-ol and the derived ester, 2-acetoxy-5,5,5-trifluoropent-3-yne". . p. 39 - 49. Retrieved 1993.
• 2、 Taylor et al.. "". . p. 1064. Retrieved 1962.
• 3、 Vakhtin, A. B.,Petrov, A. K.. "INTRACAVITY ABSORPTION OF He-nE-LASER RADIATION AS A DIRECT TIME-RESOLVED PROBE OF R + NO -> RNO REACTION KINETICS (R = C3F7, CF3, CH3)". . p. 603 - 606. Retrieved 1990.
• 4、 Singh, Rajendra P.,Shreeve, Jean'ne M.. "Perfluoroalkylation of simple inorganic molecules: A one step route to novel perfluoroalkylated compounds". . p. 1818 - 1819. Retrieved 2002.
• 5、 Park et al.. "". . p. 1462. Retrieved 1962.
• 6、 Green, Michael J.,Tipping, Anthony E.. "The reaction of perfluoro-2,5-diazahexane 2,5-dioxyl with aromatic compounds and perfluoroiodoalkanes". . p. 237 - 242. Retrieved 1994.
• 7、 Zeng, Xiaoqing,Beckers, Helmut,Willner, Helge,Neuhaus, Patrik,Grote, Dirk,Sander, Wolfram. "Photochemistry of matrix isolated (Trifluoromethyl)sulfonyl azide, CF3SO2N3". . p. 2281 - 2288. Retrieved 2015/03/30.