methyl 2-methylidenehexanoate

Base Information

• Chemical Name: methyl 2-methylidenehexanoate
• CAS No.: 3070-68-6
• Molecular Formula: C8H14 O2
• Molecular Weight: 142.198
• Mol file: 3070-68-6.mol

Synonyms:Methyl2-butyl-2-propenoate; Methyl 2-butylacrylate; Methyl 2-methylenehexanoate;Methyl a-butylacrylate; NSC 319473

Chemical Property of methyl 2-methylidenehexanoate

Chemical Property:

• Vapor Pressure: 1.57mmHg at 25°C
• Boiling Point: 169.1°Cat760mmHg
• Flash Point: 47.8°C
• Density: 0.894g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl 2-methylidenehexanoate

There total 1 articles about methyl 2-methylidenehexanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

Trifluoro-methanesulfonate(2-acetyl-2-methoxycarbonyl-hexyl)-phenyl-trimethylsilanylmethyl-sulfonium; (139413-35-7) → 1-(phenylsulfanyl)acetone (5042-53-5) + methyl α-butylacrylate (3070-68-6) + methyl (phenylsulfanyl)acetate (17277-58-6)

Guidance literature:

With 4 A molecular sieve; tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; for 3h;

DOI:10.1246/cl.1992.159

Reference yield: 93.0%

methyl α-butylacrylate (3070-68-6) + 1-(1-(phenylsulfonyl)but-3-ynylsulfonyl)benzene (151993-29-2) → C23H26O4S2

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 55 ℃; for 12h;

DOI:10.1021/ja049079o

Reference yield: 90.0%

methyl α-butylacrylate (3070-68-6) + 1-cyclopropyl-3-(3,5-dimethylphenyl)urea (64392-97-8) → C20H30N2O3

Guidance literature:

With C₄₂H₃₄F₁₀IrN₄⁽¹⁺⁾*C₁₁₀H₁₄₀BN₂O₁₂^(1-); In dichloromethane; at -20 ℃; for 12h; enantioselective reaction; Inert atmosphere; Irradiation;

DOI:10.1039/d1ob00126d

upstream raw materials:

Trifluoro-methanesulfonate(2-acetyl-2-methoxycarbonyl-hexyl)-phenyl-trimethylsilanylmethyl-sulfonium;

Downstream raw materials:

1-methyl cyclopentyl (meth)acrylate

2-Cyclopentylmethyl-hexanoic acid methyl ester

3-Cyclohexyl-2-(cyclohexylmethyl)propionsaeure-methylester

methyl 2-(cyclohexylmethyl)acrylate

Refernces