Ethyl propyl ether

Base Information

• Chemical Name: Ethyl propyl ether
• CAS No.: 628-32-0
• Molecular Formula: C5H12 O
• Molecular Weight: 88.1497
• Hs Code.: 29093090
• European Community (EC) Number: 211-036-3
• UN Number: 2615
• DSSTox Substance ID: DTXSID5075286
• Nikkaji Number: J43.342J
• Wikidata: Q3591984
• Mol file: 628-32-0.mol

Synonyms:ETHYL PROPYL ETHER;1-Ethoxypropane;628-32-0;Propane, 1-ethoxy-;Ethyl n-propyl ether;Ether, ethyl propyl;Propyl ethyl ether;EINECS 211-036-3;UN2615;3-Ethoxypropane;Propano, 1-etoxi-;n-C3H7OC2H5;1-Ethoxypropane, AldrichCPR;DTXSID5075286;NVJUHMXYKCUMQA-UHFFFAOYSA-;NA2615;UN 2615;LS-67843;E0052;D90426;Ethyl propyl ether [UN2615] [Flammable liquid];Ethyl propyl ether [UN2615] [Flammable liquid];Q3591984

Chemical Property of Ethyl propyl ether

Chemical Property:

• Appearance/Colour: off-white to brown crystalline powder and chunks
• Vapor Pressure: 181mmHg at 25°C
• Melting Point: -127.5°C
• Refractive Index: 1.3680-1.3710
• Boiling Point: 62 °C
• Flash Point: <-20oC
• PSA: 9.23000
• Density: 0.74
• LogP: 1.43290
• Storage Temp.: 0-10°C
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 88.088815002
• Heavy Atom Count: 6
• Complexity: 19.9
• Transport DOT Label: Flammable Liquid

Purity/Quality:

98% ^*data from raw suppliers

Ethyl Propyl Ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,Xn
• Hazard Codes: Xn
• Statements: 22

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCOCC
• Uses: Ethyl Propyl Ether (cas# 628-32-0) is used in the composition of methanol fuel for vehicles which solves the problems of vehicle methanol fuel meeting water and low temperature stratification, rubber swelling, metal corrosion, hot air resistance, and cold start.

Technology Process of Ethyl propyl ether

There total 53 articles about Ethyl propyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

3-ethoxyprop-1-ene (557-31-3) → ethylpropylether (628-32-0)

Guidance literature:

With tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex; (bis[(2-dicyclohexylphosphino)ethyl]amine)cobalt(II)(CH₂SiMe₃); hydrogen; In tetrahydrofuran; at 50 ℃; for 24h; under 760.051 Torr;

Reference yield: 63.0%

Triethyl orthopropionate (115-80-0) → 1,1-diethoxypropane (4744-08-5) + ethylpropylether (628-32-0)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In n-heptane; at 150 ℃; under 67506.8 Torr; Temperature;

Reference yield: 42.2%

diazomethane (186581-53-3,908094-01-9,334-88-3) + diethyl ether (60-29-7,927820-24-4) → ethyl methyl ether (540-67-0) + ethylpropylether (628-32-0) + 2-butyl ethyl ether (625-54-7)

Guidance literature:

Product distribution; Mechanism; Ambient temperature; Irradiation;

DOI:10.1021/jo00186a007

upstream raw materials:

diazomethane

diethyl ether

propan-1-ol

ethanol

Downstream raw materials:

Dimethyl ether

ethyl methyl ether

methyl propyl ether

2-butyl ethyl ether

Refernces

• 1、 Silakova, A. A.,Mishin, I. V.,Vasserberg, V. E.. "CONVERSION OF ETHERS ON DEHYDRATION CATALYSTS. 5. DISPROPORTIONATION OF ETHERS ON ZEOLITE CATALYSTS". . p. 909 - 913. Retrieved 1983.
• 2、 Shin, Hyunseo,Moon, Bongjin. "Careful investigation of the hydrosilylation of olefins at poly(ethylene glycol) chain ends and development of a new silyl hydride to avoid side reactions". . p. 527 - 536. Retrieved 2018/01/27.
• 3、 Zhang, Guoqi,Scott, Brian L.,Hanson, Susan K.. "Mild and homogeneous cobalt-catalyzed hydrogenation of C=C, C=O, and C=N bonds". supporting information. p. 12102 - 12106. Retrieved 2013/01/16.