9-Tridecenoic acid, 13-(4-benzoylphenyl)-, (9Z)-

Base Information

• Chemical Name: 9-Tridecenoic acid, 13-(4-benzoylphenyl)-, (9Z)-
• CAS No.: 874140-88-2
• Molecular Formula: C26H32O3
• Molecular Weight: 392.538
• Mol file: 874140-88-2.mol

Synonyms:

Chemical Property of 9-Tridecenoic acid, 13-(4-benzoylphenyl)-, (9Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-Tridecenoic acid, 13-(4-benzoylphenyl)-, (9Z)-

There total 6 articles about 9-Tridecenoic acid, 13-(4-benzoylphenyl)-, (9Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

4-((Z)-13-hydroxytridec-4-enyl)benzophenone (874140-87-1) → (Z)-13-(4-benzoylphenyl)-9-tridecenoic acid (874140-88-2)

Guidance literature:

With dipyridinium dichromate; In N,N-dimethyl-formamide; at 20 ℃; for 48h;

DOI:10.1021/jo052030w

Reference yield:

4-(13-hydrohytridec-4-ynyl)benzophenone (874140-86-0) → (Z)-13-(4-benzoylphenyl)-9-tridecenoic acid (874140-88-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 97 percent / hydrogen / Lindlar catalyst / methanol

2: 87 percent / PDC / dimethylformamide / 48 h / 20 °C

With dipyridinium dichromate; hydrogen; Lindlar's catalyst; In methanol; N,N-dimethyl-formamide;

DOI:10.1021/jo052030w

Reference yield:

4-(13-(tetrahydro-2H-pyran-2-yloxy)tridec-4-ynyl)benzophenone (874140-85-9) → (Z)-13-(4-benzoylphenyl)-9-tridecenoic acid (874140-88-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 93 percent / PPTS / methanol / 3 h / Heating

2: 97 percent / hydrogen / Lindlar catalyst / methanol

3: 87 percent / PDC / dimethylformamide / 48 h / 20 °C

With dipyridinium dichromate; hydrogen; pyridinium p-toluenesulfonate; Lindlar's catalyst; In methanol; N,N-dimethyl-formamide;

DOI:10.1021/jo052030w

upstream raw materials:

4-((Z)-13-hydroxytridec-4-enyl)benzophenone

4-(13-hydrohytridec-4-ynyl)benzophenone

4-(13-(tetrahydro-2H-pyran-2-yloxy)tridec-4-ynyl)benzophenone

2-dec-9-ynyloxy-tetrahydro-pyran

Downstream raw materials:

1-O-(13-(4-benzoylphenyl)-9-(Z)-tridecenoyl)-2-O-methoxymethyl-sn-glycerol

1-O-methoxymethyl-2-O-(13-(4-benzoylphenyl)-9-(Z)-tridecenoyl)-sn-glycerol

1-((Z)-13-(4-benzoylphenyl)-9-tridecenoyl)-sn-glycerol

(Z)-13-benzoylphenyl-9-tridecenoic acid (S)-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl ester

Refernces