Technology Process of Acetic acid, (phenylthio)-, 3,7-dimethyl-2,6-octadienyl ester, (E)-
There total 1 articles about Acetic acid, (phenylthio)-, 3,7-dimethyl-2,6-octadienyl ester, (E)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1.) SeO2, 2.) cyanoborohydride / 1.) pyridine, 95percent ethanol, reflux, 4.5 h, 2.) THF, pH 3, 1 h, 0 deg C then 23 deg C, 18 h
2: 99.8 percent / CBr4, triphenylphosphine / diethyl ether / 20 h / 23 °C
3: 37 percent / NaH (oil) / hexamethylphosphoric acid triamide; tetrahydrofuran / 23 h / 93 °C
With
selenium(IV) oxide; cyanoborane; carbon tetrabromide; sodium hydride; triphenylphosphine;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether;
DOI:10.1021/jo00173a043
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 1.) SeO2, 2.) cyanoborohydride / 1.) pyridine, 95percent ethanol, reflux, 4.5 h, 2.) THF, pH 3, 1 h, 0 deg C then 23 deg C, 18 h
2: 99.8 percent / CBr4, triphenylphosphine / diethyl ether / 20 h / 23 °C
With
selenium(IV) oxide; cyanoborane; carbon tetrabromide; triphenylphosphine;
In
diethyl ether;
DOI:10.1021/jo00173a043
