ALLYLMAGNESIUM BROMIDE

Base Information

• Chemical Name: ALLYLMAGNESIUM BROMIDE
• CAS No.: 1730-25-2
• Molecular Formula: C3H5BrMg
• Molecular Weight: 145.282
• Hs Code.: 29319090
• Mol file: 1730-25-2.mol

Synonyms:Allylmagnesiumbromide (6CI);Magnesium, allylbromo- (7CI,8CI);2-Propenylmagnesium bromide;Allylbromomagnesium;Bromo(2-propenyl)magnesium;

Chemical Property of ALLYLMAGNESIUM BROMIDE

Chemical Property:

• Flash Point: -40 °C
• PSA: 0.00000
• Density: 0.851 g/cm³
• LogP: 1.98560
• Storage Temp.: Refrigerator
• Sensitive.: air sensitive, moisture sensitiv

Purity/Quality:

99% ^*data from raw suppliers

Allyl magnesium bromide solution ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+; C
• Hazard Codes: F+,C,F
• Statements: 12-14/15-19-22-34-66-67-11
• Safety Statements: 9-16-29-33-43-45-36/37/39-26

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Uses: Allylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize:2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine tarchonanthuslactone(+)-preussinpolyhydroxylated quinolizidine alkaloids

Technology Process of ALLYLMAGNESIUM BROMIDE

There total 18 articles about ALLYLMAGNESIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

diallylamine (124-02-7) → allylmagnesium bromide (1730-25-2)

Guidance literature:

With triethylamine;

Reference yield: 82.0%

→ allylmagnesium bromide (1730-25-2)

Guidance literature:

Reference yield: 73.0%

→ tricyclo[4.2.1.02,5 ]non-7-en-3-ylmethanol (53201-70-0) + allylmagnesium bromide (1730-25-2)

Guidance literature:

upstream raw materials:

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

allyl bromide

1,3-dibromo-propane

1,3-bis(bromomagnesio)propane

Downstream raw materials:

n-Pent-4-enyl alcohol

2-n-Propylquinoline

2-allyl-1,2-dihydro-quinoline

1-(2-pyridinyl)but-3-en-1-ol

Refernces

• 1、 Furuta, Miyu,Hanaya, Kengo,Sugai, Takeshi,Shoji, Mitsuru. "Synthesis of trans,trans,cis-fused tetracyclic skeleton via radical domino cyclization". . p. 2316 - 2322. Retrieved 2017.
• 2、 Boukattaya, Fatma,Caillé, Julien,Ammar, Houcine,Rouzier, Florian,Boeda, Fabien,Pearson-Long, Morwenna S. M.,Bertus, Philippe. "A Short Access to Symmetrically α,α-Disubstituted α-Amino Acids from Acyl Cyanohydrins". . p. 906 - 916. Retrieved 2016/03/12.