Plastoquinol 1

Base Information

• Chemical Name: Plastoquinol 1
• CAS No.: 58700-70-2
• Molecular Formula: C13H18O2
• Molecular Weight: 206.285
• Hs Code.: 2907299090
• Mol file: 58700-70-2.mol

Synonyms:2,3-dimethyl-5-(3-methyl-but-2-enyl)-benzene-1,4-diol;2,3-Dimethyl-5-(3-methyl-but-2-enyl)hydrochinon;

Chemical Property of Plastoquinol 1

Chemical Property:

• PSA: 40.46000
• LogP: 3.22330

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Plastoquinol 1

There total 3 articles about Plastoquinol 1 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

2,3-dimethyl-1,4-benzoquinone (526-86-3) + prenyl tributylstannane (104108-29-4) → 5-(3-methyl-2-butenyl)-2,3-dimethylhydroquinone (58700-70-2)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃;

DOI:10.1021/ja00531a019

Reference yield:

2-methyl-3-buten-2-ol (115-18-4) + 2,3-dimethyl-1,4-dihydroxybenzene (608-43-5) → 5-(3-methyl-2-butenyl)-2,3-dimethylhydroquinone (58700-70-2)

Guidance literature:

With boron trifluoride diethyl etherate; In 1,4-dioxane;

DOI:10.1006/jmra.1995.1189

Reference yield:

→ 5-(3-methyl-2-butenyl)-2,3-dimethylhydroquinone (58700-70-2)

Guidance literature:

2,3-Dimethylchinon, Allylzinn 2c, BF3*Et2O;

DOI:10.1021/jo00413a045

upstream raw materials:

2,3-dimethyl-1,4-benzoquinone

prenyl tributylstannane

2-methyl-3-buten-2-ol

2,3-dimethyl-1,4-dihydroxybenzene

Downstream raw materials:

2,3-dimethyl-5-(3-methyl-2-buten-1-yl)-2,5-cyclohexadiene-1,4-dione

Refernces

• 1、 Rohrer, M.,Plato, M.,Macmillan, F.,Grishin, Y.,Lubitz, W.,Moebius, K.. "Orientation-Selected 95 GHz High-Field ENDOR Spectroscopy of Randomly Oriented Plastoquinone Anion Radicals". . p. 59 - 66. Retrieved 2007/10/03.