Aluminum, hydrodiphenyl-

Base Information

• Chemical Name: Aluminum, hydrodiphenyl-
• CAS No.: 880-08-0
• Molecular Formula: C₁₂H₁₁Al
• Molecular Weight: 182.201
• Mol file: 880-08-0.mol

Synonyms:

Chemical Property of Aluminum, hydrodiphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Aluminum, hydrodiphenyl-

There total 2 articles about Aluminum, hydrodiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

AlH3·0.19Et2O + triphenylaluminium (841-76-9) → diphenylaluminium hydride (880-08-0)

Guidance literature:

In toluene; at 75 ℃; for 3h; Inert atmosphere; Schlenk technique;

DOI:10.1002/zaac.201300484

Reference yield:

aluminium hydride (7784-21-6) + triphenylaluminium (841-76-9) → diphenylaluminium hydride (880-08-0)

Guidance literature:

In tetrahydrofuran; Ph3Al:AlH3=2:1, stirred for 15h at room temp., under dry N2; elem. anal.;

Reference yield:

diphenylaluminium hydride (880-08-0) → Li(1+)*AlH(C6H5)3(1-)=LiAlH(C6H5)3 (62126-58-3)

Guidance literature:

With phenyllithium; In diethyl ether; LiPh:AlH3=1:1, stirred at room temp. for 1h; elem. anal.;

upstream raw materials:

aluminium hydride

triphenylaluminium

Downstream raw materials:

Li⁽¹⁺⁾*AlH(C₆H₅)3^(1-)=LiAlH(C₆H₅)3

Refernces

• 1、 Ashby, E. C.,Goel, A. B.. "Redistribution Reactions Involving Lithium Aluminium Hydride and Lithium Tetraphenylaluminate". . p. 134 - 138. Retrieved 2007/10/02.