Didodecyl Sulfoxide

Base Information

• Chemical Name: Didodecyl Sulfoxide
• CAS No.: 2168-96-9
• Molecular Formula: C24H50OS
• Molecular Weight: 386.726
• Hs Code.: 2930909090
• European Community (EC) Number: 218-513-5
• UNII: D8U5EMC3SR
• DSSTox Substance ID: DTXSID40176071
• Nikkaji Number: J299.137C
• Wikidata: Q83046402
• Mol file: 2168-96-9.mol

Synonyms:Didodecyl Sulfoxide;2168-96-9;1-(Dodecylsulfinyl)dodecane;1-dodecylsulfinyldodecane;di-n-Dodecyl sulfoxide;Dodecyl Sulfoxide;1,1'-Sulphinylbisdodecane;Dodecane,1-(dodecylsulfinyl)-;EINECS 218-513-5;D8U5EMC3SR;SCHEMBL669556;Dodecane, 1-(dodecylsulfinyl)-;DTXSID40176071;CAA16896;MFCD00039865;AKOS024390805;CS-0357939;D2885;FT-0634085;T70572;A925059

Chemical Property of Didodecyl Sulfoxide

Chemical Property:

• Melting Point: 91 °C
• Boiling Point: 505.1 °C at 760 mmHg
• Flash Point: 259.3 °C
• PSA: 36.28000
• Density: 0.89 g/cm³
• LogP: 9.44260
• Solubility.: soluble in dichloromethane
• XLogP3: 10.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 22
• Exact Mass: 386.35823739
• Heavy Atom Count: 26
• Complexity: 251

Purity/Quality:

98% ^*data from raw suppliers

Didodecyl Sulfoxide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCCCCCCS(=O)CCCCCCCCCCCC

Technology Process of Didodecyl Sulfoxide

There total 5 articles about Didodecyl Sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

didodecyl sulfide (2469-45-6) + C19H26N2O11Se (1233477-18-3) → didodecyl sulfoxide (2168-96-9) + C19H26N2O10Se (1233477-09-2)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 23 ℃; for 2h;

DOI:10.1021/ol1010032

Reference yield: 99.0%

didodecyl sulfide (2469-45-6) → didodecyl sulfoxide (2168-96-9)

Guidance literature:

With nitrourea; silica-gel-supported sulfuric acid; ammonium bromide; In dichloromethane; at 20 ℃; for 0.85h;

DOI:10.1007/BF03246211

Reference yield:

1-dodecylthiol (112-55-0) → didodecyl sulfoxide (2168-96-9)

Guidance literature:

With dihydrogen peroxide; In tert-butyl alcohol;

DOI:10.1021/jo01032a054

upstream raw materials:

didodecyl sulfide

1-dodecylthiol

1-dodecylbromide

C₁₉H₂₆N₂O₁₁Se

Downstream raw materials:

didodecyl sulfide

dodecane

Refernces

• 1、 Heidari, Leili,Shiri, Lotfi. "CoFe2O4@SiO2-CPTES-Guanidine-Cu(II): A novel and reusable nanocatalyst for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones and polyhydroquinolines and oxidation of sulfides". . . Retrieved 2019/01/11.
• 2、 Tamoradi, Taiebeh,Ghadermazi, Mohammad,Ghorbani-Choghamarani, Arash,Molaei, Somayeh. "Synthesis and characterization of oxo-vanadium complex anchored onto SBA-15 as a green, novel and reusable nanocatalyst for the oxidation of sulfides and oxidative coupling of thiols". . p. 4259 - 4276. Retrieved 2018/03/21.