Bromotetradecylmagnesium

Base Information

• Chemical Name: Bromotetradecylmagnesium
• CAS No.: 88303-25-7
• Molecular Formula: C14H29BrMg
• Molecular Weight: 301.593
• Hs Code.: 2931900090
• Mol file: 88303-25-7.mol

Synonyms:tetradecylmagnesium bromide;tetradecylmagnesium chloride;n-myristylmagnesium bromide;

Chemical Property of Bromotetradecylmagnesium

Chemical Property:

• PSA: 0.00000
• LogP: 6.50070

Purity/Quality:

97% ^*data from raw suppliers

1-Tetradecylmagnesiumbromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bromotetradecylmagnesium

There total 1 articles about Bromotetradecylmagnesium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-fluoro-N-(exo-2-norbornyl)-p-toluenesulfonamide (103731-48-2) + 1-Bromotetradecane (112-71-0) → tetradecylmagnesium bromide (88303-25-7)

Guidance literature:

With magnesium; In toluene;

Reference yield: 70.0%

fluoroacetonitrile (503-20-8) + tetradecylmagnesium bromide (88303-25-7) → 1-fluorohexadecan-2-one

Guidance literature:

fluoroacetonitrile; tetradecylmagnesium bromide; In diethyl ether; at 0 ℃; Inert atmosphere;

With hydrogenchloride; water; In diethyl ether; Inert atmosphere;

DOI:10.1016/j.tetlet.2011.07.125

Reference yield: 15.0%

tetradecylmagnesium bromide (88303-25-7) → 1‐fluorotetradecane (593-33-9)

Guidance literature:

With p-tolylSO₂NF(exo-2-norbornyl); In diethyl ether; toluene; at -78 ℃;

DOI:10.1021/ja00314a050

upstream raw materials:

N-fluoro-N-(exo-2-norbornyl)-p-toluenesulfonamide

1-Bromotetradecane

Downstream raw materials:

2,3-dimethylheptadecane

pentadecanol

octacosane

1-tetradecylboronic acid

Refernces