2,7-DINITROPHENAZINE

Base Information

• Chemical Name: 2,7-DINITROPHENAZINE
• CAS No.: 72848-48-7
• Molecular Formula: C12H6 N4 O4
• Molecular Weight: 270.204
• Hs Code.: 2933990090
• Mol file: 72848-48-7.mol

Synonyms:2,7-Dinitrophenazine

Chemical Property of 2,7-DINITROPHENAZINE

Chemical Property:

• Vapor Pressure: 5.88E-11mmHg at 25°C
• Boiling Point: 534.4°C at 760 mmHg
• Flash Point: 277°C
• PSA: 117.42000
• Density: 1.61g/cm³
• LogP: 3.64580

Purity/Quality:

99% ^*data from raw suppliers

2,7-DINITROPHENAZINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,7-DINITROPHENAZINE

There total 8 articles about 2,7-DINITROPHENAZINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

2-iodo-4-nitrophenylamine (6293-83-0) → 2,7-dinitrophenazine (72848-48-7)

Guidance literature:

With 2Na⁽¹⁺⁾*CuC₆H₄(NCHC₆H₃OO₃S)2^(2-)=CuC₆H₄(NCHC₆H₃ONaO₃S)2; tetrabutylammomium bromide; potassium carbonate; In water; at 120 ℃; for 30h;

DOI:10.1016/j.jorganchem.2011.12.030

Reference yield: 66.0%

→ 2,7-dinitrophenazine (72848-48-7)

Guidance literature:

With iron(III) chloride; tetrabutylammomium bromide; L-proline lithium salt; sodium hydroxide; In water; at 100 ℃; for 0.5h; Microwave irradiation;

Reference yield: 44.0%

2-bromo-4-nitroaniline (13296-94-1) → 2,7-dinitrophenazine (72848-48-7)

Guidance literature:

With 2Na⁽¹⁺⁾*CuC₆H₄(NCHC₆H₃OO₃S)2^(2-)=CuC₆H₄(NCHC₆H₃ONaO₃S)2; tetrabutylammomium bromide; potassium carbonate; In water; at 120 ℃; for 30h;

DOI:10.1016/j.jorganchem.2011.12.030

upstream raw materials:

4'-nitrobenzenesulfenanilide

4-nitro-N²-(4-nitrophenyl)-N¹,N²-bis(phenylthio)-o-phenylenediamine

4-nitro-aniline

2-iodo-4-nitrophenylamine

Refernces

• 1、 Yu, Lintao,Zhou, Xiangge,Wu, Di,Xiang, Haifeng. "Synthesis of phenazines by Cu-catalyzed homocoupling of 2-halogen anilines in water". supporting information; experimental part. p. 75 - 78. Retrieved 2012/04/17.
• 2、 Balboni, Claudio,Benati, Luisa,Montevecchi, P. Carlo,Spagnolo, Piero. "Benzenesulphenanilidyl Radicals. Part 2. Substituent and Solvent Effects on the Reactivity of 4'-Substituted Benzenesulphenanilidyl Radicals Produced by Oxidation with Lead Dioxide of the Corresponding Benzenesulphenanilides". . p. 2111 - 2117. Retrieved 2007/10/02.