4-(2-ethylhexyl)bromobenzene

Base Information

• Chemical Name: 4-(2-ethylhexyl)bromobenzene
• CAS No.: 883903-22-8
• Molecular Formula: C₁₄H₂₁Br
• Molecular Weight: 269.225
• Mol file: 883903-22-8.mol

Synonyms:1-Bromo-4-(2-ethylhexyl)benzene;4-(2-Ethylhexyl)phenyl bromide;

Chemical Property of 4-(2-ethylhexyl)bromobenzene

Chemical Property:

• PSA: 0.00000
• LogP: 5.20800

Purity/Quality:

HPLC≥98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(2-ethylhexyl)bromobenzene

There total 4 articles about 4-(2-ethylhexyl)bromobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

3-bromomethylheptane (18908-66-2) + 1.4-dibromobenzene (106-37-6) → 1-bromo-4-(2'-ethylhexyl)benzene (883903-22-8)

Guidance literature:

3-bromomethylheptane; With magnesium; In tetrahydrofuran; diethyl ether; for 1.5h; Reflux; Inert atmosphere;

1.4-dibromobenzene; With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; diethyl ether; at 0 - 20 ℃; for 20h; Inert atmosphere;

DOI:10.1134/S1070428019010056

Reference yield: 77.6%

3-(chloromethyl)heptane (123-04-6) + 4-Bromophenylboronic acid (5467-74-3) → 1-bromo-4-(2'-ethylhexyl)benzene (883903-22-8)

Guidance literature:

With potassium phosphate; palladium diacetate; DavePhos; In 1,4-dioxane; for 4h; Reflux;

Reference yield: 36.0%

3-bromomethylheptane (18908-66-2) + 1,4-bromoiodobenzene (589-87-7) → 1-bromo-4-(2'-ethylhexyl)benzene (883903-22-8)

Guidance literature:

3-bromomethylheptane; With magnesium; In diethyl ether; at 50 ℃; for 12h;

1,4-bromoiodobenzene; With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; zinc dibromide; In tetrahydrofuran; diethyl ether; at 0 - 55 ℃; for 40h;

DOI:10.1021/ma302404y

upstream raw materials:

3-bromomethylheptane

1,4-bromoiodobenzene

1.4-dibromobenzene

3-(chloromethyl)heptane

Downstream raw materials:

C₁₇H₂₄N₂

Refernces

• 1、 Vanga, Mukundam,Sahoo, Ashutosh,Lalancette, Roger A.,J?kle, Frieder. "Linear Extension of Anthracene via B←N Lewis Pair Formation: Effects on Optoelectronic Properties and Singlet O2 Sensitization". . . Retrieved 2021/12/23.
• 2、 -. "ORGANIC COMPOUNDS, LIGHE EMITTING DIODE AND LIGHT EMITTING DEVICE HAVING THE COMPOUNDS". Paragraph 0189; 0193-0195. . Retrieved 2019/08/06.