1-HYDROXYDICYCLOPENTADIENE

Base Information

• Chemical Name: 1-HYDROXYDICYCLOPENTADIENE
• CAS No.: 6814-80-8
• Molecular Formula: C10H12 O
• Molecular Weight: 148.2
• Hs Code.: 2906299090
• Mol file: 6814-80-8.mol

Synonyms:4,7-Methanoinden-1-ol,3a,4,7,7a-tetrahydro- (6CI,7CI,8CI); NSC 160534

Chemical Property of 1-HYDROXYDICYCLOPENTADIENE

Chemical Property:

• Vapor Pressure: 0.00189mmHg at 25°C
• Boiling Point: 259.4°C at 760 mmHg
• PKA: 14.07±0.20(Predicted)
• Flash Point: 92.8°C
• PSA: 20.23000
• Density: 1.204g/cm³
• LogP: 1.35540

Purity/Quality:

99%, ^*data from raw suppliers

1-HYDROXYDICYCLOPENTADIENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-HYDROXYDICYCLOPENTADIENE

There total 2 articles about 1-HYDROXYDICYCLOPENTADIENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → Tricyclo<5.2.1.02.6>deca-4,8-dien-3-ol (875-20-7,6814-80-8,24529-79-1,24708-29-0,57386-40-0,88555-62-8,105367-92-8,122919-96-4,123930-79-0) + C10H10O + C10H12O2 (29987-76-6) + C10H12O

Guidance literature:

With oxygen; In acetonitrile; at 25 ℃; for 24h; Reagent/catalyst; Sealed tube; Irradiation; Green chemistry;

DOI:10.1039/d0cy02352c

Reference yield:

endo-Dicyclopentadien (1755-01-7,25038-78-2) → endo-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one (5530-96-1,15584-54-0,61139-01-3,85806-41-3,105500-35-4,111136-75-5,699-82-1,150738-84-4) + endo-9-Oxatetracyclo<5.3.1.02.6.08.10>undec-3-ene (4387-46-6,52154-84-4,52882-08-3) + 4-Hydroxytricyclo<5.2.1.02,6>deca-3,8-diene (875-20-7,6814-80-8,24529-79-1,24708-29-0,57386-40-0,88555-62-8,105367-92-8,122919-96-4,123930-79-0) + 3,8-dioxapentacyclo<6.3.1.02,4.06,11.07,9>dodecane (81-21-0,19773-45-6,24560-94-9,70681-73-1,70681-74-2,4168-48-3,29987-76-6) + C10H12O2 (87753-42-2) + C10H12O (4387-45-5,52154-83-3,52882-09-4,91109-11-4)

Guidance literature:

With oxygen; In chlorobenzene; at 90 ℃; Kinetics; also other temperatures;

Reference yield: 94.0%

benzoyl chloride (98-88-4) + (-)-endo-3-hydroxydicyclopentadiene (875-20-7,6814-80-8,24529-79-1,24708-29-0,57386-40-0,88555-62-8,105367-92-8,123930-79-0,122919-96-4) → C17H16O2 (105259-45-8)

Guidance literature:

With pyridine; at 20 ℃; for 10h;

DOI:10.1016/j.tetlet.2012.03.087

upstream raw materials:

cyclopenta-1,3-diene

endo-Dicyclopentadien

Downstream raw materials:

3-Cyclopentenon

(+/-)-exo-3-acetoxydicyclopentadiene

cyclopent-2-enone

cyclopenta-1,3-diene

Refernces

• 1、 Schnurpfeil, D.. "Dicyclopentadiene Oxidation I. Uncatalyzed Liquid-Phase Oxidation of Dicyclopentadiene". . p. 481 - 488. Retrieved 2007/10/02.