N-TERT-BUTYLETHYLAMINE

Base Information

• Chemical Name: N-TERT-BUTYLETHYLAMINE
• CAS No.: 4432-77-3
• Molecular Formula: C6H15N
• Molecular Weight: 101.192
• Hs Code.: 2921199990
• Mol file: 4432-77-3.mol

Synonyms:Diethylamine,1,1-dimethyl- (7CI,8CI);1,1-Dimethyldiethylamine;Ethyl-tert-butylamine;tert-Butylethylamine;

Chemical Property of N-TERT-BUTYLETHYLAMINE

Chemical Property:

• Vapor Pressure: 51.5mmHg at 25°C
• Melting Point: -87.87°C (estimate)
• Refractive Index: 1.404
• Boiling Point: 92.5 °C at 760 mmHg
• PKA: 10.76±0.28(Predicted)
• PSA: 12.03000
• Density: 0.742 g/cm³
• LogP: 1.78530

Purity/Quality:

99% ^*data from raw suppliers

N-tert-Butylethylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 10-34-36-25
• Safety Statements: 16-26-36-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-TERT-BUTYLETHYLAMINE

There total 7 articles about N-TERT-BUTYLETHYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

N-tert-butylacetamide (762-84-5) → N-t-butylethylamine (4432-77-3)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 60h; Heating;

DOI:10.1021/ja00169a029

Reference yield:

N-tert-butyl-N-ethyl-tert-octylamine → 2,4,4-trimethyl-1-pentene (107-39-1) + N-t-butylethylamine (4432-77-3)

Guidance literature:

In ⁽²⁾H₈-toluene; at 100 ℃;

DOI:10.1021/acs.joc.8b00496

Reference yield:

C14H22N2O → N-t-butylethylamine (4432-77-3) + N-(tert-Butyl)ethylidenamin-N-oxid (55830-07-4) + 1,3-dibenzylurea (1466-67-7) + C14H22N2O2

Guidance literature:

With dihydrogen peroxide; In [D₃]acetonitrile; water; at 37 ℃; for 24h;

DOI:10.1002/ejoc.201801307

upstream raw materials:

N-tert-butylacetamide

methanol

1-tert-butyl-1-ethyl-3-phenylurea

N-methyl-tert-butylamine

Downstream raw materials:

Ethyl-tert-butyl-nitroso-amin

1,4-di-tert-butyl-1,4-diazabutadiene

glyoxime-N_.N'-diphenyl ether

azoxybenzene

Refernces

• 1、 Ying, Hanze,Yang, Yingfeng,Cai, Kaimin,Cheng, Jianjun. "Hindered urea bond: A bilaterally responsive chemistry to hydrogen peroxide". supporting information. p. 728 - 731. Retrieved 2019/01/24.
• 2、 Cai, Kaimin,Ying, Hanze,Cheng, Jianjun. "Dynamic Ureas with Fast and pH-Independent Hydrolytic Kinetics". supporting information. p. 7345 - 7348. Retrieved 2018/06/11.